Nucleophilic substitution in the l-nitro-4-chloroanthraquinone by phenolates and thiophenolates

Nucleophilic substitution in the l-nitro-4-chloroanthraquinone by phenolates and thiophenolates Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 1998, Volume: 34, Number: 6, Pages: 861-866 Pages count : 6

Authors

Tabatskaya A.A. ¹ , Beregovaya I.V. ¹ , Vlasov V.M. ¹

Affiliations

1	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russian Federation

In reactions of l-nitro-4-chloroanthraquinone with phenolate anions first is chiefly substituted the chlorine atom, whereas by the thiophenolate anion predominantly is replaced the nitro group. The difference in behavior with this substrate of the O- and S-nucleophiles is attributed to the change in the proportion of electrostatic and orbital interaction. © 1998 MAHK Hayka/Interperiodica Publishing.

Tabatskaya A.A. , Beregovaya I.V. , Vlasov V.M.
Nucleophilic substitution in the l-nitro-4-chloroanthraquinone by phenolates and thiophenolates
Russian Journal of Organic Chemistry. 1998. V.34. N6. P.861-866. Scopus РИНЦ

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