Influence of the matrix composition on the properties of fluorinated graphite inclusion compounds with acetonitrile

Influence of the matrix composition on the properties of fluorinated graphite inclusion compounds with acetonitrile Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236

Output data

Year: 2005, Volume: 50, Number: 7, Pages: 1055-1061 Pages count : 7

Authors

Chekhova G.N. ¹ , Ukraintseva E.A. ¹ , Ivanov I.M. ¹ , Yudanov N.F. ¹ , Shubin Yu.V. ¹ , Logvinenko V.A. ¹ , Pinakov D.V. ¹ , Fadeeva V.P. ² , Alferova N.I. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent' eva 3, Novosibirsk, 630090, Russian Federation
2	Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russian Federation

The stoichiometry and thermal, kinetic, and thermodynamic stability of fluorinated graphite inclusion compounds with acetonitrile C2F x, where 0.5 < x < 1.0, were studied as dependent on the composition (architecture) of the matrix using physicochemical methods (DTA, X-ray crystallography, calorimetry, IR spectroscopy). Under isothermal conditions (25°C) and for 0.7 < x < 1.0, the properties intrinsic to the inclusion compound based on the limiting matrix composition C2F (digraphite monofluoride) dominate. The monotone trends of most of the properties studied indicate the berthollide character of partially fluorinated graphite and its inclusion compounds. Copyright © 2005 by Pleiades Publishing, Inc.

Chekhova G.N. , Ukraintseva E.A. , Ivanov I.M. , Yudanov N.F. , Shubin Y.V. , Logvinenko V.A. , Pinakov D.V. , Fadeeva V.P. , Alferova N.I.
Influence of the matrix composition on the properties of fluorinated graphite inclusion compounds with acetonitrile
Russian Journal of Inorganic Chemistry. 2005. V.50. N7. P.1055-1061. WOS Scopus РИНЦ

Чехова Г.Н. , Украинцева Э.А. , Иванов И.М. , Юданов Н.Ф. , Шубин Ю.В. , Логвиненко В.А. , Пинаков Д.В. , Фадеева В.П. , Алферова Н.И.
Влияние состава матрицы на свойства соединений включения фторированного графита с ацетонитрилом
Журнал неорганической химии. 2005. Т.50. №7. С.1143-1149. РИНЦ

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Scopus	2-s2.0-25144488568
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