Photochemical transformations of terpenoids in the presence of cyclodextrins

Photochemical transformations of terpenoids in the presence of cyclodextrins Full article

Journal

Russian Journal of Nondestructive Testing
ISSN: 1061-8309

Output data

Year: 1997, Volume: 33, Number: 2, Pages: 183-193 Pages count : 11

Authors

Luzina O.A. ¹ , Tatarova L.E. ¹ , Korchagina D.V. ¹ , Salakhutdinov N.F. ¹ , Barkhash V.A. ¹

Affiliations

1	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Lavrent'eva 9, Novosibirsk, 630090, Russian Federation

The effect of complexation of terpene compounds with cyclodextrins on photolysis depends on the type of cyclodextrin and on the structure of the initial substrates. In some cases, only a change in the reaction rate is observed; in other cases, the complexation results in allylic rearrangements, hydride and acyl shifts, and cyclization with the formation of four-, five-, and six-membered cycles, whereas only cis-trans isomerization reactions are observed in the absence of complexation. © 1997 MAEe cyrllic signK Hayκa/Interperiodica Publishing.

Luzina O.A. , Tatarova L.E. , Korchagina D.V. , Salakhutdinov N.F. , Barkhash V.A.
Photochemical transformations of terpenoids in the presence of cyclodextrins
Russian Journal of Nondestructive Testing. 1997. V.33. N2. P.183-193. Scopus РИНЦ

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