Possibility of nonclassic reaction between episulfonium and episelenonium cycles and a double bond: π-Complexes of 1,2,3,3,4,5,6,6-octamethyl-1,4-cyclohexadiene with cations of RE+ type (E = S, Se)

Possibility of nonclassic reaction between episulfonium and episelenonium cycles and a double bond: π-Complexes of 1,2,3,3,4,5,6,6-octamethyl-1,4-cyclohexadiene with cations of RE+ type (E = S, Se) Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 1998, Volume: 34, Number: 11, Pages: 1563-1568 Pages count : 6

Authors

Borodkin G.I. ¹ , Chernyak E.I. ¹ , Shakirov M.M. ¹ , Shubin V.G. ¹

Affiliations

1	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russian Federation

As demonstrated by 1Hand 13C NMR spectroscopy the interaction of 1,2,3,3,4,5,6,6-octamethyl-1,4-cyclohexadiene with cations RS+ (R = CH3, C6H5, C6F5) and RSe+ (R = C6H5, C6F5) results in formation of π-complexes of type with lack of nonclassic interaction between episulfonium or episelenium cycle and a double bond not directly bonded. The complexes studied are not prone to π,π-rearrangement. ©1998 MAHK "Hayka/Interperiodica".

Borodkin G.I. , Chernyak E.I. , Shakirov M.M. , Shubin V.G.
Possibility of nonclassic reaction between episulfonium and episelenonium cycles and a double bond: π-Complexes of 1,2,3,3,4,5,6,6-octamethyl-1,4-cyclohexadiene with cations of RE+ type (E = S, Se)
Russian Journal of Organic Chemistry. 1998. V.34. N11. P.1563-1568. Scopus РИНЦ

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