Analysis of influence of substituents on electrochemical oxidation and reduction potentials of aromatic and heterocyclic compounds, on the basis of the dependence of electronic effects of the substituents in π-systems on the character of the π-molecular orbitals

Analysis of influence of substituents on electrochemical oxidation and reduction potentials of aromatic and heterocyclic compounds, on the basis of the dependence of electronic effects of the substituents in π-systems on the character of the π-molecular orbitals Full article

Journal

Theoretical and Experimental Chemistry
ISSN: 0040-5760

Output data

Year: 1995, Volume: 31, Number: 3, Pages: 127-139 Pages count : 13 DOI: 10.1007/BF00538784

Authors

Vasil'eva N.V. ¹ , Starichenko V.F. ¹ , Koptyug V.A. ¹

Affiliations

1	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Academician Lavrent'ev Prospect, Novosibirsk, 630090, Russian Federation

The influence of substituents on the electrochemical potentials of aromatic and heterocyclic π-systems has been analyzed from the standpoint of the relationship between the electronic effects of the substituents and the structure of the π-molecular orbitals. The proposed calculational schemes and parametrization can be used for quantitative estimates of the magnitudes of the electrochemical oxidation and reduction potentials of substituted aromatic and heterocyclic compounds. © 1995 Plenum Publishing Corporation.

Vasil'eva N.V. , Starichenko V.F. , Koptyug V.A.
Analysis of influence of substituents on electrochemical oxidation and reduction potentials of aromatic and heterocyclic compounds, on the basis of the dependence of electronic effects of the substituents in π-systems on the character of the π-molecular orbitals
Theoretical and Experimental Chemistry. 1995. V.31. N3. P.127-139. DOI: 10.1007/BF00538784 Scopus РИНЦ

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