Chemical properties of ylidene derivatives of azines. 4. Structures of the products of protonation and transformation of dihydroazinylidenecyanoacetic esters in concentrated sulfuric acid Full article
| Journal |
Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353 |
||
|---|---|---|---|
| Output data | Year: 1990, Volume: 26, Number: 7, Pages: 801-807 Pages count : DOI: 10.1007/BF00509712 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
It was demonstrated by UV and 13C NMR spectroscopy that in concentrated sulfuric acid ylidene derivatives of dihydropyridine (Ia) and dihydropyridazine (IIa) have aromatic structures Ib and IIb, while derivatives of dihydropyrimidines IIIa and IVa, dihydropyrazine Va, and dihydro-s-triazine VIa retain ylidene structures IIIb-VIb, respectively, which determines their greater stability in these solutions. When solutions of Ib-VIb in 95% H2SO4 were allowed to stand, they were converted to the corresponding azinylmalonic ester monoamides or azinylacetamides, depending on the reaction temperature. © 1991 Plenum Publishing Corporation.
Cite:
Oleinik I.V.
, Zagulyaeva O.A.
, Denisov A.Y.
, Mamaev V.P.
Chemical properties of ylidene derivatives of azines. 4. Structures of the products of protonation and transformation of dihydroazinylidenecyanoacetic esters in concentrated sulfuric acid
Chemistry of Heterocyclic Compounds. 1990. V.26. N7. P.801-807. DOI: 10.1007/BF00509712 Scopus РИНЦ
Chemical properties of ylidene derivatives of azines. 4. Structures of the products of protonation and transformation of dihydroazinylidenecyanoacetic esters in concentrated sulfuric acid
Chemistry of Heterocyclic Compounds. 1990. V.26. N7. P.801-807. DOI: 10.1007/BF00509712 Scopus РИНЦ
Dates:
| Published print: | Jul 1, 1990 |
Identifiers:
| Scopus | 2-s2.0-34249926009 |
| Elibrary | 30891424 |
| OpenAlex | W2321534484 |