Synthesis and mesomorphic properties of aryl 5-alkyl-(and alkoxy) pyrimidine-2-carboxylates

Synthesis and mesomorphic properties of aryl 5-alkyl-(and alkoxy) pyrimidine-2-carboxylates Full article

Journal

Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353

Output data

Year: 1986, Volume: 22, Number: 9, Pages: 994-1001 Pages count : DOI: 10.1007/BF00478133

Authors

Mikhaleva M. A. , Save?ev V. A. , Pavlyuchenko A. I. , Grebenkin M. F. , Mamaev V. P.

Affiliations

1	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk, 630090, Russian Federation
2	(Scopus) Research Institute for Organic Intermediates and Dyes, Moscow, 103787, Russian Federation

Some aryl 5-alkyl(and alkoxy)pyrimidine-2-carboxylates (I) and 5-alkylpyrimidinoyloxybenzoates (II) have been obtained. It has been found the former do not display mesomorphism, but the latter are nematic liquid crystals with a range over which the mesophase exists of 50-90‡C. The transition to the liquid crystal state in these compounds takes place at approximately the same temperatures as in their benzene analogues, but the thermal stability of the mesophase is somewhat less. Cyano-derivatives of pyrimidine effectively increase the value of the dielectric anisotropy of the matrix mixture, but they have a marked effect on its clarification temperature. © 1987 Plenum Publishing Corporation.

Mikhaleva M.A. , Save?ev V.A. , Pavlyuchenko A.I. , Grebenkin M.F. , Mamaev V.P.
Synthesis and mesomorphic properties of aryl 5-alkyl-(and alkoxy) pyrimidine-2-carboxylates
Chemistry of Heterocyclic Compounds. 1986. V.22. N9. P.994-1001. DOI: 10.1007/BF00478133 Scopus РИНЦ

Published print:

Sep 1, 1986

Scopus	2-s2.0-34250100954
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