Reaction of difluoromethyl pentafluorophenyl sulfoxide with nucleophiles

Reaction of difluoromethyl pentafluorophenyl sulfoxide with nucleophiles Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2017, Volume: 53, Number: 7, Pages: 1012-1016 Pages count : 5 DOI: 10.1134/S1070428017070089

Authors

Koshcheev B.V. ¹ , Maksimov A.M. ¹ , Platonov V.E. ¹ , Shelkovnikov V.V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia

Reactions of 1-(difluoromethanesulfinyl)pentafluorobenzene with sodium methoxide, sodium phenoxide, potassium hydrosulfide, and methylamine resulted in substitution of fluorine atom in the 4-position (in the reaction with methylamine, also in the 2-position). Treatment of the title compound with sodium hydroxide afforded pentafluorobenzene due to cleavage of the C(arom)aEuro'S bond.

Koshcheev B.V. , Maksimov A.M. , Platonov V.E. , Shelkovnikov V.V.
Reaction of difluoromethyl pentafluorophenyl sulfoxide with nucleophiles
Russian Journal of Organic Chemistry. 2017. V.53. N7. P.1012-1016. DOI: 10.1134/S1070428017070089 WOS Scopus РИНЦ

Кощеев Б.В. , Максимов А.М. , Платонов В.Е. , Шелковников В.В.
Взаимодействие дифторметил(пентафторфенил)сульфоксида с нуклеофилами
Журнал органической химии (RUSS J ORG CHEM+). 2017. Т.51. №7. С.1001-1005. РИНЦ

Published print:	Jul 1, 2017
Published online:	Aug 30, 2017

Web of science	WOS:000408707900008
Scopus	2-s2.0-85028623468
Elibrary	31057757
OpenAlex	W2751649395