Reaction of 1,3- hydroxylamino oximes with formaldehyde, acetaldehyde, and acetone

Reaction of 1,3- hydroxylamino oximes with formaldehyde, acetaldehyde, and acetone Full article

Journal

Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353

Output data

Year: 1977, Volume: 13, Number: 2, Pages: 201-207 Pages count : DOI: 10.1007/BF00497878

Authors

Tikhonov A. Ya. , Volodarskii L. B.

Affiliations

1	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk, 630090, Russian Federation

The products of condensation of 1,3-hydroxylamino oximes with formaldehyde have 1-hydroxy-1,2,5,6-tetrahydropyrimidine 3-oxide (cyclic form) structures, the products of condensation with acetone have N-(3-oximino-substituted)-α,α-dimethylnitrone (open form) structures, and the products of condensation with acetaldehyde exist in solution in the form of a tautomeric mixture of the open and cyclic forms. The products of condensation of alkyl-aromatic 1,3-hydroxylamino oximes with acetaldehyde have N-(3-oximino-substituted)-α-nitrone (open form) structures. © 1977 Plenum Publishing Corporation.

Tikhonov A.Y. , Volodarskii L.B.
Reaction of 1,3- hydroxylamino oximes with formaldehyde, acetaldehyde, and acetone
Chemistry of Heterocyclic Compounds. 1977. V.13. N2. P.201-207. DOI: 10.1007/BF00497878 Scopus РИНЦ

Published print:

Feb 1, 1977

Scopus	2-s2.0-34250292654
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OpenAlex	W1981076022