Polyfluorinated oxacalixarenes. Interaction of perfluoro-m-xylene with resorcinol and tetrafluororesorcinol

Polyfluorinated oxacalixarenes. Interaction of perfluoro-m-xylene with resorcinol and tetrafluororesorcinol Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2017, Volume: 199, Pages: 52-59 Pages count : 8 DOI: 10.1016/j.jfluchem.2017.04.010

Tags

Macrocycles; Polyfluorinated oxacalixarenes; Perfluoro-m-xylene; Tetrafluororesorcinol; Resorcinol; X-ray diffraction

Authors

Kovtonyuk Vladimir N. ¹ , Gatilov Yuri V. ^1,2

Affiliations

1	(Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

Interaction of perfluoro-m-xylene with tetrafluororesorcinol in Et3N-CH3CN system leads to the formation of perfluorinated tetramethyltetraoxacalix[4]arene with a good yield, while the reaction with resorcinol gives a mixture of macrocycles containing 4, 6 or 8 aromatic rings. The intermediate products in these reactions are perfluoro-3-(2,4-dimethylphenoxy)phenol and 1,3-bis(2,4-bistrifluoromethyltrifluorophenoxy)benzene, respectively. The interaction of the latter with tetrafluororesorcinol leads to the formation of tetraoxacalix[4]arene of ABAC type with a good yield.

Kovtonyuk V.N. , Gatilov Y.V.
Polyfluorinated oxacalixarenes. Interaction of perfluoro-m-xylene with resorcinol and tetrafluororesorcinol
Journal of Fluorine Chemistry. 2017. V.199. P.52-59. DOI: 10.1016/j.jfluchem.2017.04.010 WOS Scopus РИНЦ

Published print:

Jul 1, 2017

Web of science	WOS:000404204300008
Scopus	2-s2.0-85019157812
Elibrary	31022886
OpenAlex	W2607583354