(Pentafluorobenzoyl)acetic ester Full article
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Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 |
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| Output data | Year: 1965, Volume: 14, Number: 10, Pages: 1762-1766 Pages count : DOI: 10.1007/BF00850155 | ||
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Abstract:
1. Two methods were developed for the synthesis of (pentafluorobenzoyl)acetic ester: by the condensation of pentafluorobenzoyl chloride with the ethoxymagnesium derivative of malonic ester with subsequent partial hydrolysis and decarboxylation, and by the ester condensation of ethyl pentafluorobenzoate with ethyl acetate in presence of bromo(diisopropylamino)magnesium. 2. In the condensation of ethyl pentafluorobenzoate with sodioacetoacetic ester, as a result of nucleophilic substitution and subsequent hydrolysis, diethyl tetrafluorohomoterephthalate is formed. By the hydrolysis of the latter with partial decarboxylation, (2,3,5,6-tetrafluorophenyl)acetate acid was obtained. © 1966 Consultants Bureau.
Cite:
Prudchenko A.T.
, Barkhash V.A.
, Vorozhtsov N.N.
(Pentafluorobenzoyl)acetic ester
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1965. V.14. N10. P.1762-1766. DOI: 10.1007/BF00850155 Scopus
(Pentafluorobenzoyl)acetic ester
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1965. V.14. N10. P.1762-1766. DOI: 10.1007/BF00850155 Scopus
Dates:
| Published print: | Oct 1, 1965 |
Identifiers:
| Scopus | 2-s2.0-34250584114 |
| OpenAlex | W2075468141 |