Binuclear Pd(II) complexes with chiral ethylenediaminodioxime (H 2L) and bis-α-thiooxime (H2L1), the derivative of monoterpenoid(+)-3-carene. Crystal structures of [Pd 2(H2L)Cl4] and [Pd2(H 2L1)Cl4] • 3CDCl3

Binuclear Pd(II) complexes with chiral ethylenediaminodioxime (H 2L) and bis-α-thiooxime (H2L1), the derivative of monoterpenoid(+)-3-carene. Crystal structures of [Pd 2(H2L)Cl4] and [Pd2(H 2L1)Cl4] • 3CDCl3 Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2008, Volume: 34, Number: 2, Pages: 115-128 Pages count : 14 DOI: 10.1134/s1070328408020073

Authors

Kokina T.E. ¹ , Myachina L.I. ¹ , Glinskaya L.A. ¹ , Tkachev A.V. ² , Klevtsova R.F. ¹ , Sheludyakova L.A. ¹ , Bizyaev S.N. ² , Agafontsev A.M. ² , Gorshkov N.B. ³ , Larionov S.V. ¹

Affiliations

1	(Scopus) Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090, Russian Federation
2	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation
3	(Scopus) Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russian Federation

Diamagnetic Pd(II) complexes with the chiral ethylenediaminodioxime (H 2 L) and bis-α-thiooxime (H2L1), the derivatives of monoterpenoid (+)-3-carene, of the composition Pd2(H 2L)Cl4(I), Pd2(H2L 1)Cl4 (II), and the solvate Pd2(H 2L1)Cl4•3DCl3 (III) were synthesized. The crystal structures of complex I and solvate III were determined from X-ray diffraction data. The structures consist of acentric binuclear molecules with the coordination cores PdN2Cl2 (in I) and PdNSCl2 (in III) in the form of the distorted squares. In complex I, each Pd atom coordinates two N atoms of the tetradentate bridge-cyclic ligand H2L and two Cl atoms; in compound III, one N and one S atom of the tetradentate bridge-cyclic ligand H2L1, and 2 Cl atoms. The CDCl3 molecules in compound III lie in the cavities formed by the molecules of complex II. In both structures, the PdCl2 fragments are in the trans-positions. The 1H NMR spectra indicate that the structures of complexes I, II in solutions are similar to the structures of compounds I, III in the solid state. © 2008 MAIK Nauka.

Kokina T.E. , Myachina L.I. , Glinskaya L.A. , Tkachev A.V. , Klevtsova R.F. , Sheludyakova L.A. , Bizyaev S.N. , Agafontsev A.M. , Gorshkov N.B. , Larionov S.V.
Binuclear Pd(II) complexes with chiral ethylenediaminodioxime (H 2L) and bis-α-thiooxime (H2L1), the derivative of monoterpenoid(+)-3-carene. Crystal structures of [Pd 2(H2L)Cl4] and [Pd2(H 2L1)Cl4] • 3CDCl3
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2008. V.34. N2. P.115-128. DOI: 10.1134/s1070328408020073 WOS Scopus РИНЦ

Кокина Т.Е. , Мячина Л.И. , Глинская Л.А. , Ткачев А.В. , Клевцова Р.Ф. , Шелудякова Л.А. , Бизяев С.Н. , Агафонцев А.М. , Горшков Н.Б. , Ларионов С.В.
Синтез двухъядерных соединений палладия(II) с хиральными этилендиаминдиоксимом (H2L) и бис- -тиооксимом (H2L1) производными монотерпеноида (+)-3-карена. кристаллические структуры [Pd2(H2l)Cl4] и [Pd2(H2L1)Cl4] ·3CdCl3
Координационная химия (RUSS J COORD CHEM+). 2008. Т.34. №2. С.120-132. РИНЦ

Published print:	Feb 1, 2008
Published online:	Jan 18, 2011

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