Abstract: An approach to the synthesis of a series of bis(arene)chromium complexes with a varied substituent in one of the ligands has been worked out, which involves low-temperature co-condensation of chromium vapours with arenes followed by the modification of substituents in arene ligands. In this way a series of complexes have been obtained: (η-C6H5Cl)(η-C6H5X)C r+A- (X = H, NMe2, {A figure is presented}, {A figure is presented}, {A figure is presented} OMe, OEt, OPr-i, OBu-N, Cl, CO2H, CO2Me, CF3); (η-C6H6)- (η-XC6H4Cl)Cr+A- (X = H, P-NMe2, p-OMe, m-OMe, p-Me, m-Me, p-Cl, m-Cl, p-CO2Me, m-CO2Me, p-CO2H, m-CO2H, (A- = PF6-, BPh4-); (η-C6H5X)(η-C6H5CO 2H)Cr+PF6- (X = H, OPr-i, OBu-n, OMe, Me, Cl, CO2H, CO2Me, CF3); (η-C6H6)(η-XC6H4CO 2H)Cr+PF6- (X = H, p-OMe, m-OMe, p-Me, p-Cl, m-Cl, p-CO2H, p-CO2Me); (η-C6H5CO2H)(η-C6 H5X)Cr (X = H, Cl, CF3, CO2Me, CO2H, OMe). © 1986.

Cite: Litvak V.V. , Kun P.P. , Oleynik I.I. , Volkov O.V. , Shteingarts V.D.
Arene transition metal complexes in reactions with nucleophilic agents. XII. The synthesis of a series of bis(arene)chromium complexes with a varied substituent in one of the ligands
Journal of Organometallic Chemistry. 1986. V.310. N2. P.189-201. DOI: 10.1016/S0022-328X(00)99552-4 WOS Scopus

Dates:

Published print:

Aug 1, 1986

Identifiers:

Web of science	WOS:A1986D720400006
Scopus	2-s2.0-50849149037
OpenAlex	W1581444768

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