Synthesis of perfluoroalkyl(Methoxy)borates and -boranes

Synthesis of perfluoroalkyl(Methoxy)borates and -boranes Full article

Journal

Main Group Metal Chemistry
ISSN: 0792-1241

Output data

Year: 2009, Volume: 32, Number: 3, Pages: 109-114 Pages count : 6 DOI: 10.1515/MGMC.2009.32.3.109

Authors

Adonin Nicolay Yu. ¹ , Bardin Vadim V. ² , Frohn Hermann-Josef ³

Affiliations

1	(Scopus) G.K. Boreskov Institute of Catalysis, SB RAS, Lavrent 'ev Ave. 5, 630090 Novosibirsk, Russian Federation
2	(Scopus) N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, SB RAS, Acad. Lavrent'ev Ave. 9, 630090 Novosibirsk, Russian Federation
3	(Scopus) Department of Chemistry, Inorganic Chemistry, University of Duisburg-Essen, Lotharstr. 1, D-47048 Duisburg, Germany

Interaction of lithium perfluoroalkyltrimethoxyborates, Li[C nF2n+IB(OMe)3] (n = 3, 4, 6), with ClSiMe 3 results in formation of the corresponding esters C nF2n+IB(OMe)2 in 93-95 % yields. They are sufficiently stable both CH2Cl2 and etherical solvents (etiler, THF) and react with C2F5Li to give Li[(C nF2n+I)(C2F5)B(OMe)2]. Metathesis of the latter with KF leads to corresponding potassium salts.

Adonin N.Y. , Bardin V.V. , Frohn H-J.
Synthesis of perfluoroalkyl(Methoxy)borates and -boranes
Main Group Metal Chemistry. 2009. V.32. N3. P.109-114. DOI: 10.1515/MGMC.2009.32.3.109 WOS Scopus РИНЦ

Published print:

Jan 1, 2009

Web of science	WOS:000274081400001
Scopus	2-s2.0-76149129732
Elibrary	41743139
OpenAlex	W2320437571