Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization

Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization Full article

Journal

Chemical Communications
ISSN: 1359-7345

Output data

Year: 2019, Volume: 55, Number: 2, Pages: 190-193 Pages count : 4 DOI: 10.1039/C8CC08541B

Authors

Edeleva M. ^1,2 , Morozov D. ^1,2 , Parkhomenko D. ¹ , Polienko Y. ^1,2 , Iurchenkova A. ^1,2 , Kirilyuk I. ^1,2 , Bagryanskaya E. ^1,2

Affiliations

1	(Scopus) N.N. Vorozhtsov Institute of Organic Chemistry SB RAS, 9 Pr. Lavrentjeva, Novosibirsk, 630090, Russian Federation
2	(Scopus) Novosibirsk State University, 2 Pirogova Str., Novosibirsk, 630090, Russian Federation

An alkoxyamine was prepared from a cyclic aldonitrone nitroxide. The resulting alkoxyamine containing an aldonitrone functional substituent is relatively stable but can react readily with vinyl monomers to form a cycloadduct that has a much higher C-ON homolysis rate. This type of in situ activation converts the aldonitrone alkoxyamine into an efficient controlling agent for nitroxide-mediated polymerization. Here we present a study on this reaction of C-ON bond homolysis and application of such an alkoxyamine as an in situ-activated initiator. © The Royal Society of Chemistry.

Edeleva M. , Morozov D. , Parkhomenko D. , Polienko Y. , Iurchenkova A. , Kirilyuk I. , Bagryanskaya E.
Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization
Chemical Communications. 2019. V.55. N2. P.190-193. DOI: 10.1039/C8CC08541B WOS Scopus РИНЦ

Web of science	WOS:000453911200006
Scopus	2-s2.0-85058902122
Elibrary	38645496
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