A dinuclear Re(I) tricarbonyl complex showing thermochromic luminescence

A dinuclear Re(I) tricarbonyl complex showing thermochromic luminescence Full article

Journal

Inorganic Chemistry Communications
ISSN: 1387-7003

Output data

Year: 2020, Volume: 119, Article number : 108058, Pages count : DOI: 10.1016/j.inoche.2020.108058

Tags

Phosphorescence; Re(I) complexes; Tetraphosphine ligands; Thermochromic luminescence

Authors

Petyuk M.Y. ¹ , Berezin A.S. ¹ , Bagryanskaya I.Y. ² , Artyushin O.I. ³ , Brel V.K. ³ , Arte?ev A.V. ¹

Affiliations

1	(Scopus) Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3, Acad. Lavrentiev Ave., Novosibirsk, 630090, Russian Federation
2	(Scopus) N. N. Vorozhtsov, Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9, Acad. Lavrentiev Ave., Novosibirsk, 630090, Russian Federation
3	(Scopus) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28, Vavilova Str., Moscow, 119991, Russian Federation

A dinuclear Re(I) tricarbonyl complex, [Re2(CO)6(L)Br2], has been synthesized by the reaction of 1,2,4,5-tetrakis(diphenylphosphino)benzene (L) with 2 equiv. of Re(CO)5Br. In the solid state at 300 K, this complex emits untypical yellow-green phosphorescence (λmax ≈ 530 nm), which, upon cooling to 77 K, strongly enhances, the color of the complex turning to turquoise (λmax ≈ 505 nm). © 2020 Elsevier B.V.

Petyuk M.Y. , Berezin A.S. , Bagryanskaya I.Y. , Artyushin O.I. , Brel V.K. , Arte?ev A.V.
A dinuclear Re(I) tricarbonyl complex showing thermochromic luminescence
Inorganic Chemistry Communications. 2020. V.119. 108058 . DOI: 10.1016/j.inoche.2020.108058 WOS Scopus РИНЦ

Published print:

Sep 1, 2020

Web of science	WOS:000564595600001
Scopus	2-s2.0-85087891756
Elibrary	45475721
OpenAlex	W3035930039