A 1D Coordination Polymer Based on CuI and 2-(Diphenylphosphino)Pyrimidine: Synthesis, Structure and Luminescent Properties

A 1D Coordination Polymer Based on CuI and 2-(Diphenylphosphino)Pyrimidine: Synthesis, Structure and Luminescent Properties Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2020, Volume: 61, Number: 6, Pages: 894-898 Pages count : 5 DOI: 10.1134/S0022476620060086

Tags

coordination polymers; crystal structure; Cu(I) iodide; luminescence; P,N-ligands; phosphines

Authors

Davydova M.P. ¹ , Rakhmanova M.I. ¹ , Bagryanskaya I.Y. ² , Brylev K.A. ¹ , Arte?ev A.V. ¹

Affiliations

1	(Scopus) Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation
2	(Scopus) Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation

1-D chain coordination polymer (CP) of [Cu2I2(PymPPh2)]n type has been synthesized reacting CuI with 2-(diphenylphosphino)pyrimidine (PymPPh2) under mild conditions (MeCN, r.t.). The structure of the CP is imagined by double-stranded (Cu2I2)n ribbons, the Cu atoms of which are bridged by the PymPPh2 ligands in a 1,3-N,P fashion. At ambient temperature the solid-state CP manifests broad-band photoluminescence (λmax = 530 nm) with the average lifetime of 1.2 µs and quantum efficiency being 15%. © 2020, Pleiades Publishing, Ltd.

Davydova M.P. , Rakhmanova M.I. , Bagryanskaya I.Y. , Brylev K.A. , Arte?ev A.V.
A 1D Coordination Polymer Based on CuI and 2-(Diphenylphosphino)Pyrimidine: Synthesis, Structure and Luminescent Properties
Journal of Structural Chemistry. 2020. V.61. N6. P.894-898. DOI: 10.1134/S0022476620060086 WOS Scopus РИНЦ

Davydova M.P. , Rakhmanova M.I. , Bagryanskaya I.Y. , Brylev K.A. , Artem'ev A.V.
A 1D Coordination Polymer Based on CuI and 2-(Diphenylphosphino)Pyrimidine: Synthesis, Structure and Luminescent Properties
Журнал структурной химии (J STRUCT CHEM+). 2020. V.61. N6. P.947-951. DOI: 10.26902/JSC_id57701 РИНЦ

Published print:	Jun 1, 2020
Published online:	Aug 8, 2020

Web of science	WOS:000558500700008
Scopus	2-s2.0-85089226715
Elibrary	45372859
OpenAlex	W3047854877