A NEW Cu(I) IODIDE COMPLEX SHOWING DEEP-RED LUMINESCENCE

A NEW Cu(I) IODIDE COMPLEX SHOWING DEEP-RED LUMINESCENCE Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2020, Volume: 61, Number: 7, Pages: 1068-1071 Pages count : 4 DOI: 10.1134/S0022476620070082

Tags

crystal structure; Cu(I) complexes; iodocuprates; photoluminescence; pyridylphosphonium salts

Authors

Artem?ev A.V. ^1,2 , Rakhmanova M.I. ^1,2 , Brylev K.A. ^1,2 , Bagryanskaya I.Y. ^2,3

Affiliations

1	(Scopus) Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation
2	(Scopus) Novosibirsk State University, Novosibirsk, Russian Federation
3	(Scopus) Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: A reaction of a [1,4-C6H4(CH2PPy3)2]Cl2 cationic ligand with CuI (MeCN, r.t.) produces an ionic [C6H4(CH2PPy3)2][C6H4(CH2PPy3Cu3I5)2] complex containing structurally unprecedented [Cu3I5]2– inorganic module in the anionic part. The title complex in the solid manifests a weak deep-red luminescence with λmax = 680 nm and lifetimes of 14 μs and 17 μs at 300 K and 77 K, respectively. © 2020, Pleiades Publishing, Ltd.

Artem?ev A.V. , Rakhmanova M.I. , Brylev K.A. , Bagryanskaya I.Y.
A NEW Cu(I) IODIDE COMPLEX SHOWING DEEP-RED LUMINESCENCE
Journal of Structural Chemistry. 2020. V.61. N7. P.1068-1071. DOI: 10.1134/S0022476620070082 WOS Scopus РИНЦ

Artem'ev A.V. , Rakhmanova M.I. , Brylev K.A. , Bagryanskaya I.Y.
A NEW Cu(I) IODIDE COMPLEX SHOWING DEEP-RED LUMINESCENCE
Журнал структурной химии (J STRUCT CHEM+). 2020. V.61. N7. P.1131-1134. DOI: 10.26902/JSC_id58729 РИНЦ

Published print:	Jul 1, 2020
Published online:	Sep 4, 2020

Web of science	WOS:000566422200008
Scopus	2-s2.0-85090239792
Elibrary	45381400
OpenAlex	W3083224440