Hybrid Photopolymer Material Based on (8-Acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl Acrylate and Thiol-Siloxane Component for Recording Microstructures: Synthesis and Optical and Thermomechanical Properties

Hybrid Photopolymer Material Based on (8-Acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl Acrylate and Thiol-Siloxane Component for Recording Microstructures: Synthesis and Optical and Thermomechanical Properties Full article

Journal

Polymer Science - Series B
ISSN: 1560-0904

Output data

Year: 2020, Volume: 62, Number: 5, Pages: 509-521 Pages count : 13 DOI: 10.1134/S1560090420050048

Authors

Derevyanko D.I. ¹ , Basistyi V.S. ¹ , Shelkovnikov V.V. ¹ , Shundrina I.K. ¹ , Bukhtoyarova A.D. ¹ , Sa?nikov G.E. ¹ , Berezhnaya V.N. ¹ , Chernonosov A.A. ²

Affiliations

1	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation
2	(Scopus) Institute of Chemical Biology and Fundamental Medicine, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation

Abstract: A transparent hybrid photopolymer material is synthesized on the basis of (8-acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl acrylate and 3-[3-(3-mercaptopropyl)-1,1,3,5-tetramethoxy-5,5-diphenyltrisiloxane]propane-1-thiol. Using NMR spectroscopy and MALDI TOF mass spectrometry, the ability of the thiol-siloxane compound to undergo spontaneous hydrolytic condensation during storage is studied. The hybrid photopolymer films were obtained at different ratio of the components (from 16 : 1 to 1 : 2), and their thermomechanical and optical properties are investigated. The values of the storage modulus (0.9–2.3 GPa), the glass transition temperature (73–111°C), and the refractive index (1.56–1.59) are determined. On the basis of the 4 : 1 hybrid composition, a replica of relief microstructures with characteristic sizes of square elements of 5 × 0.8 μm is presented. © 2020, Pleiades Publishing, Ltd.

Derevyanko D.I. , Basistyi V.S. , Shelkovnikov V.V. , Shundrina I.K. , Bukhtoyarova A.D. , Sa?nikov G.E. , Berezhnaya V.N. , Chernonosov A.A.
Hybrid Photopolymer Material Based on (8-Acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl Acrylate and Thiol-Siloxane Component for Recording Microstructures: Synthesis and Optical and Thermomechanical Properties
Polymer Science - Series B. 2020. V.62. N5. P.509-521. DOI: 10.1134/S1560090420050048 WOS Scopus РИНЦ

Деревянко Д.И. , Басистый В.С. , Шелковников В.В. , Шундрина И.К. , Бухтоярова А.Д. , Сальников Г.Е. , Бережная В.Н. , Черноносов А.А.
ГИБРИДНЫЙ ФОТОПОЛИМЕРНЫЙ МАТЕРИАЛ НА ОСНОВЕ (8-АКРИЛОИЛ-1,4-ДИТИА-8-АЗАСПИРО[4.5]ДЕКАН-2-ИЛ)МЕТИЛ АКРИЛАТА И ТИОЛ-СИЛОКСАНОВОГО КОМПОНЕНТА ДЛЯ ЗАПИСИ МИКРОСТРУКТУР: СИНТЕЗ, ОПТИЧЕСКИЕ И ТЕРМОМЕХАНИЧЕСКИЕ СВОЙСТВА
Высокомолекулярные соединения. Серия Б. 2020. Т.52. №5. С.382-394. DOI: 10.31857/S2308113920050046 РИНЦ

Published print:	Sep 1, 2020
Published online:	Oct 30, 2020

Web of science	WOS:000583051100009
Scopus	2-s2.0-85092576310
Elibrary	45228111
OpenAlex	W3096449152