Bi(III) compounds with the thiols 4-CF3C6F4SH and 2,4-(CF3)2C6F3SH and Bi(III) and Sb(III) compounds with the mercaptophenol 2,6-Di(tert-C 4H9)-4-(CH2)3SH-C6H2OH. The crystal structure of Bi(4-CF3C6F 4S)3

Bi(III) compounds with the thiols 4-CF3C6F4SH and 2,4-(CF3)2C6F3SH and Bi(III) and Sb(III) compounds with the mercaptophenol 2,6-Di(tert-C 4H9)-4-(CH2)3SH-C6H2OH. The crystal structure of Bi(4-CF3C6F 4S)3 Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236

Output data

Year: 2004, Volume: 49, Number: 4, Pages: 545-552 Pages count : 8

Authors

Larionov S.V. ¹ , Leonova T.G. ¹ , Mikhalin I.N. ³ , Klevtsova R.F. ¹ , Glinskaya L.A. ¹ , Platonov V.E. ² , Krysin A.P. ² , Maksimov A.M. ² , Fadeeva V.P. ²

Affiliations

1	(Scopus) Nikolaev Inst. of Inorg. Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090, Russian Federation
2	(Scopus) Vorozhtsov Novosibirsk Inst. O., Siberian Division, Russian Academy of Sciences, Novosibirsk, Russian Federation
3	(Scopus) Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russian Federation

The compounds Bi(4-CF3C6F4S)3 (I), Bi {2,4-(CF3)2C6F3S} 3 (II), Bi{3,5-(tert-C4H9)2-4-OH- C6H2-1-(CH2)3S}3 (III), and Sb{3,5-(tert-C4H9)2-4-OH-C 6H2-1-(CH2)3S}3 (IV) were prepared and studied by NMR, IR, and UV spectroscopy. The crystal structure of I was determined using X-ray diffraction (CAD4 diffractometer, MoK α radiation, 2027 Fhkl, R = 0.0673). The crystals of I are monoclinic: a = 13.029(2) Å, b = 24.898(4) Å, c = 8.476(1) Å, β = 103.84(1)°, space group P21/c, V = 2669.8(7) Å3, Z = 4, ρcalc = 2.379 g/cm3. The structure of I is based on monomeric molecules containing a pyramidal BiS 3 coordination core. The intermolecular contacts between the Bi and S atoms give rise to an infinite ribbon along the c axis.

Larionov S.V. , Leonova T.G. , Mikhalin I.N. , Klevtsova R.F. , Glinskaya L.A. , Platonov V.E. , Krysin A.P. , Maksimov A.M. , Fadeeva V.P.
Bi(III) compounds with the thiols 4-CF3C6F4SH and 2,4-(CF3)2C6F3SH and Bi(III) and Sb(III) compounds with the mercaptophenol 2,6-Di(tert-C 4H9)-4-(CH2)3SH-C6H2OH. The crystal structure of Bi(4-CF3C6F 4S)3
Russian Journal of Inorganic Chemistry. 2004. V.49. N4. P.545-552. WOS Scopus РИНЦ

Ларионов С.В. , Леонова Т.Г. , Михалин И.Н. , Клевцова Р.Ф. , Глинская Л.А. , Платонов В.Е. , Крысин А.П. , Максимов А.М. , Фадеева В.П.
Соединения bi(iii) с тиолами 4-cf 3c 6f 4sh, 2,4-(cf 3) 2c 6f 3sh и bi(iii), sb(iii) с меркаптофенолом 2,6-ди(трут-c 4h 9)-4-(ch 2) 3sh-c 6h 2oh. кристаллическая структура bi(4-cf 3c 6f 4s) 3
Журнал неорганической химии. 2004. Т.49. №4. С.602-609. РИНЦ

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