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Synthesis and transformations of N-butyl-3(5)-nitro-1,2,4-triazoles under the conditions of acid-catalyzed alkylation of 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols Full article

Journal Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353
Output data Year: 2020, Volume: 56, Number: 11, Pages: 1440-1448 Pages count : 9 DOI: 10.1007/s10593-020-02835-w
Tags 1-(tert-butyl)-4-(sec-butyl)-3-nitro-1,2,4-triazolium salt; 1-(sec-butyl)-3,5-dinitro-1H-1,2,4-triazole; N-(sec-butyl)-3(5)-nitro-1,2,4-triazole; alkylation; isomers; transformation of alkyl substituent; X-ray structural analysis
Authors Sukhanov Gennady T. 1 , Krupnova Irina A. 1 , Filippova Yuliya 1 , Gatilov Yurii 2 , Sukhanova Anna G. 1 , Bosov Konstantin K. 1 , Pivovarova Ekaterina 1
Affiliations
1 Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk, 659322, Russia
2 N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk, 630090, Russia

Abstract: The directions of thermodynamically controlled rearrangements and transformations of alkyl substituents under the conditions of acidcatalyzed alkylation of unsubstituted and 5(3)-substituted 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols (n-, i-, tert-, sec-BuOH) were studied.
Cite: Sukhanov G.T. , Krupnova I.A. , Filippova Y. , Gatilov Y. , Sukhanova A.G. , Bosov K.K. , Pivovarova E.
Synthesis and transformations of N-butyl-3(5)-nitro-1,2,4-triazoles under the conditions of acid-catalyzed alkylation of 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols
Chemistry of Heterocyclic Compounds. 2020. V.56. N11. P.1440-1448. DOI: 10.1007/s10593-020-02835-w WOS Scopus РИНЦ
Dates:
Published print: Nov 1, 2020
Published online: Dec 3, 2020
Identifiers:
Web of science WOS:000595754000010
Scopus 2-s2.0-85097216980
Elibrary 45098696
OpenAlex W3111972155
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