A COMPLEX OF Zn(II) WITH CHIRAL NOPINANE-ANNELATED 9,9 '-bi-4,5-DIAZAFLUORENYLIDENE: SYNTHESIS, STRUCTURE, AND PROPERTIES

A COMPLEX OF Zn(II) WITH CHIRAL NOPINANE-ANNELATED 9,9 '-bi-4,5-DIAZAFLUORENYLIDENE: SYNTHESIS, STRUCTURE, AND PROPERTIES Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2020, Volume: 61, Number: 10, Pages: 1606-1614 Pages count : 9 DOI: 10.1134/S0022476620100133

Tags

terpenes; diazafluorenylidene; complex of Zn(II); structure; photoluminecence

Authors

Kokina T.E. ¹ , Glinskaya L.A. ¹ , Piryazev D.A. ¹ , Vasiliev E.S. ² , Sheludyakova L.A. ¹ , Rakhmanova M.I. ¹ , Tkachev A.V. ²

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Complex ZnLCl2 center dot EtOH center dot H2O (I) where L is chiral 9,9 '-bi-4,5-diazafluorenylidene containing fragments of natural monoterpenoide (-)-alpha-pinene is synthesized. The crystal structure of I is composed of ZnLCl2 mononuclear complex, solvate EtOH, and H2O molecules. The coordination polyhedron Cl2N2 of the Zn atom is a distorted tetrahedron. L is a bidentate cyclic ligand, involving only two N atoms in the coordination. Complex I is characterized by IR and NMR spectroscopy and its thermal properties are analyzed. In the solid phase, L exhibits photoluminescence is the visible range (lambda(max) = 610 nm).

Kokina T.E. , Glinskaya L.A. , Piryazev D.A. , Vasiliev E.S. , Sheludyakova L.A. , Rakhmanova M.I. , Tkachev A.V.
A COMPLEX OF Zn(II) WITH CHIRAL NOPINANE-ANNELATED 9,9 '-bi-4,5-DIAZAFLUORENYLIDENE: SYNTHESIS, STRUCTURE, AND PROPERTIES
Journal of Structural Chemistry. 2020. V.61. N10. P.1606-1614. DOI: 10.1134/S0022476620100133 WOS Scopus РИНЦ

Кокина Т.Е. , Глинская Л.А. , Пирязев Д.А. , Васильев Е.С. , Шелудякова Л.А. , Рахманова М.И. , Ткачев А.В.
Комплекс zn(ii) с хиральным нопинан-аннелированным 9,9-би-4,5-диазафлуоренилиденом: синтез, структура, свойства
Журнал структурной химии (J STRUCT CHEM+). 2020. Т.61. №10. С.1690-1699. DOI: 10.26902/JSC_id61853 РИНЦ

Published print:	Oct 1, 2020
Published online:	Oct 13, 2020

Web of science	WOS:000598775100013
Scopus	2-s2.0-85106797997
Elibrary	46782701
OpenAlex	W3110872498