STRUCTURE AND LUMINESCENT PROPERTIES OF COORDINATION POLYMERS CONTAINING LEAD(II) AND THIOPHENE LIGANDS

STRUCTURE AND LUMINESCENT PROPERTIES OF COORDINATION POLYMERS CONTAINING LEAD(II) AND THIOPHENE LIGANDS Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2020, Volume: 61, Number: 11, Pages: 1800-1809 Pages count : 10 DOI: 10.1134/S002247662011013X

Tags

luminescence; metal-organic coordination polymers; single crystal X-ray diffraction analysis

Authors

Dubskikh Dubskikh V.A. ¹ , Lysova Lysova A.A. ^1,2 , Samsonenko D.G. ^1,2 , Samsonov V.A. ³ , Ryadun A.A. ¹ , Dybtsev D.N. ^1,2 , Fedin V.P. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation
2	Novosibirsk State University, Novosibirsk, Russian Federation
3	Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Three new metal-organic framework polymers [Pb2(btdc)2] (1), [Pb3(ttdc)3(dma)2] (2), and [Pb(ttdc)(dma)] (3) (H2btdc = 2,2′-bithiophene-5,5′-dicarboxylic acid, H2ttdc = thieno[3,2-b]thiophene-2,5-dicarboxylic acid, dma = N,N-dimethylacetamide) are synthesized under solvatothermal conditions. The compounds are characterized by single crystal and powder X-ray diffraction, elemental, thermogravimetric, and IR spectroscopic analyses. All three compounds are three-dimensional coordination polymers with layered (1) or chain (2, 3) motifs. The study of luminescent properties reveals the intraligand nature of radiative transitions. For 1 luminescence quenching is observed because of the strengthening of vibrational states and long-range interactions between π-systems of thiophene groups. The luminescence spectrum of 2 contains two bands corresponding to two types of ttdc2– ligands with principally different structural environments. For the ligands isolated from each other the position of the luminescence maximum corresponds to that of the free ttdc2– ion. For the ligands associated in closely packed chains by continuous π-stacking the appearance of a new maximum in the red range is observed, which is due to the delocalization of electron orbitals. © 2020, Pleiades Publishing, Ltd.

Dubskikh D.V.A. , Lysova L.A.A. , Samsonenko D.G. , Samsonov V.A. , Ryadun A.A. , Dybtsev D.N. , Fedin V.P.
STRUCTURE AND LUMINESCENT PROPERTIES OF COORDINATION POLYMERS CONTAINING LEAD(II) AND THIOPHENE LIGANDS
Journal of Structural Chemistry. 2020. V.61. N11. P.1800-1809. DOI: 10.1134/S002247662011013X WOS Scopus РИНЦ

Дубских В.А. , Лысова А.А. , Самсоненко Д.Г. , Самсонов В.А. , Рядун А.А. , Дыбцев Д.Н. , Федин В.П.
Строение и люминесцентные свойства координационных полимеров, содержащих свинец(ii) и тиофеновые лиганды
Журнал структурной химии (J STRUCT CHEM+). 2020. Т.61. №11. С.1895-1905. DOI: 10.26902/JSC_id63266 РИНЦ

Published print:	Nov 1, 2020
Published online:	Dec 25, 2020

Web of science	WOS:000602179100013
Scopus	2-s2.0-85098006635
Elibrary	45059573
OpenAlex	W3115198545