Synthesis and characterization of novel polyhalogenaromatic polyimide material for electro-optic applications

Synthesis and characterization of novel polyhalogenaromatic polyimide material for electro-optic applications Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2017, Volume: 195, Pages: 70-78 Pages count : 9 DOI: 10.1016/j.jfluchem.2017.01.010

Tags

Polycondensation; Polyfluorinated polyimides; NLO material; Second harmonic generation

Authors

Vaganova Tamara A. ¹ , Plekhanov Alexander I. ² , Simanchuk Andrey E. ² , Mikerin Sergey L. ² , Spesivtsev Evgenij V. ³ , Karpova Elena V. ^1,4 , Frolova Tatiana S. ^1,4 , Malykhin Evgenij V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Lavrentiev Ave 9, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Inst Automat & Electrometry, Siberian Branch, Koptyug Ave 1, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, AV Rzhanov Inst Semicond Phys, Siberian Branch, Lavrentiev Ave 13, Novosibirsk 630090, Russia
4	(Данные Web of science) Novosibirsk State Univ, Pirogova Str 2, Novosibirsk 630090, Russia

New highly fluorinated aromatic polyimide based on 4-chloro-2,5,6-trifluoro-1,3-phenylenediamine and 2,2-bis(3',4'-dicarboxyphenyl)hexafluoroPropane dianhydride was prepared by the two methods condensation in a solution followed by a high-temperature solid-state chain extension and one-pot high temperature polycondensation in a benzoic acid melt. The polyimide is soluble in polar amide- and ketone-type solvents, has good thermal stability and a high glass transition temperature. The polyimide films exhibit a low cut-off wavelength and excellent transparency in the UV-vis-near IR range. Low molecular weight prepolymer, formed by the solution condensation, was used to obtain the guest-host electro-optic polymer having a high glass transition temperature. The prepolymer layer doped with azochromophore DR1 (25 wt%) was subjected to a combined poling+curing procedure upon a two stepped heating in a corona discharge field. Nonlinear optical coefficient d(33) of the prepared chromophore-doped highly halogenated polyimide film measured by the Maker fringes method is 70 pm/V at the fundamental wavelength of 1064 nm and remains stable up to 85 degrees C. (C) 2017 Elsevier B.V. All rights reserved.

Vaganova T.A. , Plekhanov A.I. , Simanchuk A.E. , Mikerin S.L. , Spesivtsev E.V. , Karpova E.V. , Frolova T.S. , Malykhin E.V.
Synthesis and characterization of novel polyhalogenaromatic polyimide material for electro-optic applications
Journal of Fluorine Chemistry. 2017. V.195. P.70-78. DOI: 10.1016/j.jfluchem.2017.01.010 WOS Scopus РИНЦ

Published print:

Mar 1, 2017

Web of science	WOS:000395605000009
Scopus	2-s2.0-85010209735
Elibrary	29476863
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