Water-soluble hybrid materials based on {Mo6X8}(4+) (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate

Water-soluble hybrid materials based on {Mo6X8}(4+) (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate Full article

Journal

New Journal of Chemistry
ISSN: 1144-0546

Output data

Year: 2017, Volume: 41, Number: 4, Pages: 1670-1676 Pages count : 7 DOI: 10.1039/c6nj03469a

Authors

Svezhentseva Ekaterina V. ^1,2 , Solovieva Anastasiya O. ³ , Vorotnikov Yuri A. ¹ , Kurskaya Olga G. ⁴ , Brylev Konstantin A. ^1,2 , Tsygankova Alphiya R. ^1,2 , Edeleva Mariya V. ⁵ , Gyrylova Svetlana N. ⁴ , Kitamura Noboru ⁶ , Efremova Olga A. ⁷ , Shestopalov Michael A. ^1,2,3,4 , Mironov Yuri V. ^1,2 , Shestopalov Alexander M. ⁴

Affiliations

1	(Данные Web of science) Nikolaev Inst Inorgan Chem SB RAS, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia
3	(Данные Web of science) Sci Inst Clin & Expt Lymphol, 2 Timakova Str, Novosibirsk 630060, Russia
4	(Данные Web of science) Res Inst Expt & Clin Med, 2 Timakova Str, Novosibirsk 630060, Russia
5	(Данные Web of science) Vorozhtsov Novosibirsk Inst Organ Chem SB RAS, 9 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
6	(Данные Web of science) Hokkaido Univ, Dept Chem, Fac Sci, Sapporo, Hokkaido 0600810, Japan
7	(Данные Web of science) Univ Hull, Dept Chem, Cottingham Rd, Kingston Upon Hull HU6 7RX, N Humberside, England

The development of water-soluble forms of octahedral molybdenum clusters {Mo6X8}(4+) (X = Cl, Br, I) is strongly motivated by the tremendous potential that these complexes have for biological applications, namely as agents for bioimaging and photodynamic therapy. In this work, we report the first water-soluble hybrid materials, which represent sodium polystyrene sulfonate doped by molybdenum clusters, and the evaluation of their photophysical and biological properties (dark and photoinduced cytotoxicity and cellular uptake) with the use of cervical cancer (HeLa) and human epidermoid larynx carcinoma (Hep-2) cell-lines as models.

Svezhentseva E.V. , Solovieva A.O. , Vorotnikov Y.A. , Kurskaya O.G. , Brylev K.A. , Tsygankova A.R. , Edeleva M.V. , Gyrylova S.N. , Kitamura N. , Efremova O.A. , Shestopalov M.A. , Mironov Y.V. , Shestopalov A.M.
Water-soluble hybrid materials based on {Mo6X8}(4+) (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate

New Journal of Chemistry. 2017. V.41. N4. P.1670-1676. DOI: 10.1039/c6nj03469a WOS Scopus РИНЦ

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