Formation of 1-Aminophenazine from 3,4-Dihydrophenazin-1(2H)-one Oxime in the System Acetylene-KOH-DMSO

Formation of 1-Aminophenazine from 3,4-Dihydrophenazin-1(2H)-one Oxime in the System Acetylene-KOH-DMSO Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2017, Volume: 53, Number: 1, Pages: 150-152 Pages count : 3 DOI: 10.1134/S1070428017010316

Authors

Petrova O.V. ¹ , Sobenina L.N. ¹ , Budaev A.B. ¹ , Ivanov A.V. ¹ , Samsonov V.A. ² , Tikhonov A.Ya. ² , Trofimov B.A. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Branch, ul Favorskogo 1, Irkutsk 664033, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Pr Akademika Lavrenteva 9, Novosibirsk 630090, Russia

The reaction of 3,4-dihydrophenazin-1(2H)-one oxime with acetylene in the superbasic system KOH-DMSO afforded 1-aminophenazine in 32% yield instead of the expected pyrrolophenazine. The same product was also obtained under analogous conditions in the absence of acetylene.

Petrova O.V. , Sobenina L.N. , Budaev A.B. , Ivanov A.V. , Samsonov V.A. , Tikhonov A.Y. , Trofimov B.A.
Formation of 1-Aminophenazine from 3,4-Dihydrophenazin-1(2H)-one Oxime in the System Acetylene-KOH-DMSO
Russian Journal of Organic Chemistry. 2017. V.53. N1. P.150-152. DOI: 10.1134/S1070428017010316 WOS Scopus РИНЦ

Петрова О.В. , Собенина Л.Н. , Будаев А.Б. , Иванов А.В. , Самсонов В.А. , Тихонов А.Я. , Трофимов Б.А.
Образование 1-аминофеназина из оксима 3,4-дигидрофеназин-1(2н)-она в системе ацетилен-кон-дмсо
Журнал органической химии (RUSS J ORG CHEM+). 2017. Т.53. №1. С.151-153. РИНЦ

Published print:	Jan 1, 2017
Published online:	Mar 8, 2017

Web of science	WOS:000396525200031
Scopus	2-s2.0-85014843305
Elibrary	29490222
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