3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals

3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2017, Volume: 27, Number: 1, Pages: 19-22 Pages count : 4 DOI: 10.1016/j.mencom.2017.01.005

Authors

Volkova Yulia M. ¹ , Makarov Alexander Yu. ¹ , Zikirin Samat B. ^2,3 , Genaev Alexander M. ¹ , Bagryanskaya Irina Yu. ^1,4 , Zibarev Andrey V. ^1,5

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, VV Voevodsky Inst Chem Kinet & Combust, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk State Univ, Dept Phys, Novosibirsk 630090, Russia
4	(Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia
5	(Данные Web of science) Tomsk State Univ, Dept Chem, Tomsk 634050, Russia

The archetypal 3,1,2,4-benzothiaselenadiazine, its 5- and 8-Me3Si derivatives and related dithiadiazine and trithiadiazepine were synthesized from 2-Me3SiC6H4N=S=NSiMe3 by the action of SeCl2, SeCl4, SCl2, and S2Cl2 and converted into persistent 2,1,3-benzothiaselenazolyl and 1,2,3-benzodithiazolyl radicals characterized by EPR spectroscopy and DFT calculations.

Volkova Y.M. , Makarov A.Y. , Zikirin S.B. , Genaev A.M. , Bagryanskaya I.Y. , Zibarev A.V.
3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals
Mendeleev Communications. 2017. V.27. N1. P.19-22. DOI: 10.1016/j.mencom.2017.01.005 WOS Scopus РИНЦ

Published print:

Jan 1, 2017

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