Получение хиральных изобензофуранов на основе 3-карена в присутствии галлуазитовых нанокатализаторов [PREPARATION OF CHIRAL IZOBENZOFURANES BASED ON 3-CARENE IN THE PRESENCE OF HALLOYSITE NANOCATALYSTS]

Получение хиральных изобензофуранов на основе 3-карена в присутствии галлуазитовых нанокатализаторов [PREPARATION OF CHIRAL IZOBENZOFURANES BASED ON 3-CARENE IN THE PRESENCE OF HALLOYSITE NANOCATALYSTS] Full article

Journal

Доклады Национальной академии наук Беларуси/DOKLADY NATSIONALNOI AKADEMII NAUK BELARUS
ISSN: 1561-8323

Output data

Year: 2020, Volume: 64, Number: 4, Pages: 426-430 Pages count : 5 DOI: 10.29235/1561-8323-2020-64-4-426-430

Tags

3-carene; halloysite nanotubes; 2-carene; isobenzofurans

Authors

Sidorenko Alexander Yu ¹ , Agabekov Vladimir E. ¹ , Volcho Konstantin P. ² , Salakhutdinov Nariman F. ² , Murzin Dmitry Yu ³

Affiliations

1	(Данные Web of science) Natl Acad Sci Belarus, Inst Chem New Mat, 36 Skorina Str, Minsk 220141, BELARUS
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Novosibirsk Inst Organ Chem, 9 Lavrentiev Ave, Novosibirsk 630090, Russia
3	(Данные Web of science) Abo Akad Univ, Biskopsgatan 8, Turku 20500, Finland

The reaction of a 2-carene containing mixture, obtained by 3-carene isomerization, with 4-methoxybenzaldehyde in the presence of halloysite nanotubes treated with 5.0 % HCl was studied. The main reaction products are the chiral derivatives of isobenzofuran. Selectivity to these compounds (71.4 %) is comparable to that when only 2-carene is used as a reactant. Thus, the possibility is shown how to use halloysite nanocatalysts for selective production of isobenzofuran compounds based on 3-carene isomerization products (major component of turpentine) without preliminary mixture separation.

Sidorenko A.Y. , Agabekov V.E. , Volcho K.P. , Salakhutdinov N.F. , Murzin D.Y.
Получение хиральных изобензофуранов на основе 3-карена в присутствии галлуазитовых нанокатализаторов [PREPARATION OF CHIRAL IZOBENZOFURANES BASED ON 3-CARENE IN THE PRESENCE OF HALLOYSITE NANOCATALYSTS]

Доклады Национальной академии наук Беларуси/DOKLADY NATSIONALNOI AKADEMII NAUK BELARUS. 2020. Т.64. №4. С.426-430. DOI: 10.29235/1561-8323-2020-64-4-426-430 WOS РИНЦ

Full text from publisher

Published online:

Aug 30, 2020

Web of science	WOS:000572485800006
Elibrary	44405609
OpenAlex	W3082057609