Conjugates of Bispidine and Monoterpenoids as Ligands of Metal Complex Catalysts for the Henry Reaction

Conjugates of Bispidine and Monoterpenoids as Ligands of Metal Complex Catalysts for the Henry Reaction Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2020, Volume: 56, Number: 11, Pages: 1969-1981 Pages count : 13 DOI: 10.1134/S1070428020110123

Tags

asymmetric catalysis; cage amines; bispidines; monoterpenoids; Henry reaction; copper complexes; zinc complexes

Authors

Mozhaitsev E.S. ¹ , Ponomarev K.Yu. ¹ , Patrusheva O.S. ¹ , Medvedko A.V. ² , Dalinger A.I. ² , Rogachev A.D. ¹ , Komarova N.I. ¹ , Korchagina D.V. ¹ , Suslov E.V. ¹ , Volcho K.P. ¹ , Salakhutdinov N.F. ¹ , Vatsadze S.Z. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Novosibirsk Organ Chem Inst, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Lomonosov Moscow State Univ, Moscow 119991, Russia

A number of chiral chelating conjugates combining a bispidine central backbone and one or two pinene side fragments were synthesized. It was shown for the first time that the synthesized compounds are capable to act as catalysts in the Henry reaction both individually and in the presence of metal salts. It was found that the best catalytic results were shown for bis-tertiary amine combining bispidinone and two (-)-myrtenol fragments, and copper as well as zinc acetates.

Mozhaitsev E.S. , Ponomarev K.Y. , Patrusheva O.S. , Medvedko A.V. , Dalinger A.I. , Rogachev A.D. , Komarova N.I. , Korchagina D.V. , Suslov E.V. , Volcho K.P. , Salakhutdinov N.F. , Vatsadze S.Z.
Conjugates of Bispidine and Monoterpenoids as Ligands of Metal Complex Catalysts for the Henry Reaction
Russian Journal of Organic Chemistry. 2020. V.56. N11. P.1969-1981. DOI: 10.1134/S1070428020110123 WOS Scopus РИНЦ

Можайцев Е.С. , Пономарев К.Ю. , Патрушева О.С. , Медведько А.В. , Далингер А.И. , Рогачев А.Д. , Комарова Н.И. , Корчагина Д.В. , Суслов Е.В. , Волчо К.П. , Салахутдинов Н.Ф. , Вацадзе С.З.
КОНЪЮГАТЫ БИСПИДИНА И МОНОТЕРПЕНОИДОВ КАК ЛИГАНДЫ МЕТАЛЛОКОМПЛЕКСНЫХ КАТАЛИЗАТОРОВ РЕАКЦИИ АНРИ
Журнал органической химии (RUSS J ORG CHEM+). 2020. Т.56. №11. С.1768-1783. DOI: 10.31857/S0514749220110129 РИНЦ

Published print:	Nov 1, 2020
Published online:	Jan 25, 2021

Web of science	WOS:000607144000012
Scopus	2-s2.0-85099098106
Elibrary	45021551
OpenAlex	W3120459607