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Chlorination and decarboxylation of (heptafluoronaphthalen-2-yl)acetic acid. Synthesis of 2-(dichloromethyl)- and 2-(difluoromethyl)heptafluoronaphthalenes Full article

Journal Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393
Output data Year: 2016, Volume: 52, Number: 10, Pages: 1427-1431 Pages count : 5 DOI: 10.1134/S1070428016100092
Authors Sinyakov V.R. 1 , Mezhenkova T.V. 1 , Karpov V.M. 1 , Zonov Ya.V. 1,2
Affiliations
1 (Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia

Abstract: Decarboxylation of (heptafluoronaphthalen-2-yl)acetic acid in DMF in the presence of NaHCO3 gave 2-methylheptafluoronaphthalene, and treatment with PCl5 on heating afforded dichloro(heptafluoronaphthalen-2-yl)acetic acid. Decarboxylation of the latter in DMF led to the formation of 2-(dichloromethyl)-heptafluoronaphthalene which was converted to 2-(difluoromethyl)heptafluoronaphthalene by heating with cesium fluoride.
Cite: Sinyakov V.R. , Mezhenkova T.V. , Karpov V.M. , Zonov Y.V.
Chlorination and decarboxylation of (heptafluoronaphthalen-2-yl)acetic acid. Synthesis of 2-(dichloromethyl)- and 2-(difluoromethyl)heptafluoronaphthalenes
Russian Journal of Organic Chemistry. 2016. V.52. N10. P.1427-1431. DOI: 10.1134/S1070428016100092 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Синяков В.Р. , Меженкова Т.В. , Карпов В.М. , Зонов Я.В.
Хлорирование и декарбоксилирование (гептафторнафталин-2-ил)уксусной кислоты. синтез 2-(дихлорметил)- и 2-(дифторметил)гептафторнафталинов
Журнал органической химии (RUSS J ORG CHEM+). 2016. Т.52. №10. С.1438-1441. РИНЦ
Dates:
Published print: Oct 1, 2016
Published online: Nov 25, 2016
Identifiers:
Web of science WOS:000388982200009
Scopus 2-s2.0-84996538205
Elibrary 27578681
OpenAlex W2552882137
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