Modification of the amino group in polyfluorinated arylenediamines by reactions with aldehydes and quinones

Modification of the amino group in polyfluorinated arylenediamines by reactions with aldehydes and quinones Full article

Journal

Fluorine Notes
ISSN: 2071-4807

Output data

Year: 2018, Volume: 119, Number: 4, Pages: 5-6 Pages count : 1 DOI: 10.17677/fn20714807.2018.04.03

Tags

Polufluorinated arylenediamines, mono-N-benzylidene-polyfluoroarylenediamines, polyfluoroarylaminonaphthoquinones, chromophores

Authors

Vaganova T.A. ¹ , Chuikov I.P. ¹ , Malykhin E.V. ¹

Affiliations

1	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of Russian Academy of Sciences

Reaction of low-reactive polyfluoroaromatic diamines with benzaldehyde and hexafluoronaphthoquinone provide selective preparation of functionalized arylamines. Mono-Nbenzylidene-arylenediamines were prepared in 30-35 % yield, polyfluoroarylaminonaphthoquinones in 50- 55 % yield. The products were characterized by IR, 1H and 19F NMR spectroscopy, mass-spectrometry. Spectral characteristics of the compounds in the UV-visible range were studied and prospects of their usage as signal components of supramolecular sensors were evaluated.

Vaganova T.A. , Chuikov I.P. , Malykhin E.V.
Modification of the amino group in polyfluorinated arylenediamines by reactions with aldehydes and quinones
Fluorine Notes. 2018. Т.119. №4. С.5-6. DOI: 10.17677/fn20714807.2018.04.03 РИНЦ

Published online:

Aug 3, 2018

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