Zinc(II) Complexes with Tetrafluoroterephthalic and Octafluorobiphenyl-4,4-dicarboxylic Acid Anions and 1,10-Phenanthroline

Zinc(II) Complexes with Tetrafluoroterephthalic and Octafluorobiphenyl-4,4-dicarboxylic Acid Anions and 1,10-Phenanthroline Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2019, Volume: 89, Number: 2, Pages: 261-265 Pages count : 5 DOI: 10.1134/S1070363219020154

Tags

perfluorocarboxylic acids; zinc complexes; photoluminescence; 1; 10-phenanthroline; coordination polymers

Authors

Larionov S.V. ^1,2 , Rakhmanova M.I. ¹ , Glinskaya L.A. ¹ , Naumov D.Yu. ^1,2 , Vinogradov A.S. ³ , Karpov V.M. ³ , Platonov V.E. ³ , Fadeeva V.P. ^2,3

Affiliations

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Pr Akad Lavrenteva 3, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk Natl Res State Univ, Ul Pirogova 1, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia

Zinc(II) complexes with 1,10-phenanthroline and tetrafluoroterephthalate and octafluorobiphenyl 4,4-dicarboxylate anions have been synthesized. According to the IR spectral data, the complexation involves coordination of the metal ion to the nitrogen atoms of phenanthroline and carboxylate oxygen atom of the acid anion. The complexes show photoluminescence in the visible region of the spectrum. The structure of the complex salt [Zn(H2O)(6)][Zn(H2O)(4)(L-2)(2)] H2O, where L-2 is octafluorobiphenyl-4,4-dicarboxylate anion (monodentate ligand), has been determined by X-ray analysis.

Larionov S.V. , Rakhmanova M.I. , Glinskaya L.A. , Naumov D.Y. , Vinogradov A.S. , Karpov V.M. , Platonov V.E. , Fadeeva V.P.
Zinc(II) Complexes with Tetrafluoroterephthalic and Octafluorobiphenyl-4,4-dicarboxylic Acid Anions and 1,10-Phenanthroline
Russian Journal of General Chemistry. 2019. V.89. N2. P.261-265. DOI: 10.1134/S1070363219020154 WOS Scopus РИНЦ

Ларионов С.В. , Рахманова М.И. , Глинская Л.А. , Наумов Д.Ю. , Виноградов А.С. , Карпов В.М. , Платонов В.Е. , Фадеева В.П.
Комплексы Zn(II) с анионами тетрафтортерефталевой, октафторбифенил- 4,4'-дикарбоновой кислот и 1,10-фенантролином
Журнал общей химии (RUSS J GEN CHEM+). 2019. Т.89. №2. С.265-270. DOI: 10.1134/S0044460X1902015X РИНЦ

Published print:	Feb 1, 2019
Published online:	Apr 5, 2019

Web of science	WOS:000463789500015
Scopus	2-s2.0-85063960722
Elibrary	38665797
OpenAlex	W2927888670