Click synthesis of triazole-linked polyazamacrocycles through selective isopimaric acid transformations Full article
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Macroheterocycles
ISSN: 1998-9539 |
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| Output data | Year: 2021, Volume: 14, Number: 1, Pages: 105-111 Pages count : 7 DOI: 10.6060/mhc200817s | ||||
| Tags | CuAAC-reaction; Dialkynes; Diazides; Diterpenoids; Isopimaric acid; Macrocycles | ||||
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Abstract:
The first macrocyclic pimarane type diterpenoids containing fragments of 1,2,3-triazole and tricyclic diterpenoid isopimaric acid moieties were synthesized. The key step was the CuAAC reaction of various diazides with the dialkyne derivative obtained from 16-(carboxyphenyl)isopimaric acid. The molecular structure of the macrocyclic compound with 1,5-diazopentane unit was determined by single crystal X-ray diffraction analysis.
Cite:
Gromova M.A.
, Kharitonov Y.V.
, Rybalova T.V.
, Shults E.E.
Click synthesis of triazole-linked polyazamacrocycles through selective isopimaric acid transformations
Macroheterocycles. 2021.
V.14. N1. P.105-111. DOI: 10.6060/mhc200817s
WOS
Scopus
РИНЦ
Click synthesis of triazole-linked polyazamacrocycles through selective isopimaric acid transformations
Macroheterocycles. 2021.
V.14. N1. P.105-111. DOI: 10.6060/mhc200817s
WOS
Scopus
РИНЦ
Files:
Full text from publisher
Identifiers:
| Web of science | WOS:000659682000012 |
| Scopus | 2-s2.0-85108643262 |
| Elibrary | 46155970 |
| OpenAlex | W3174085912 |