Frequently used, but still unknown: Terbium(III) tris-hexafluoroacetylacetonate dihydrate

Frequently used, but still unknown: Terbium(III) tris-hexafluoroacetylacetonate dihydrate Full article

Journal

Inorganic Chemistry Communications
ISSN: 1387-7003

Output data

Year: 2016, Volume: 66, Pages: 47-50 Pages count : 4 DOI: 10.1016/j.inoche.2016.02.009

Tags

Crystal structure; Terbium hexafluoroacetylacetonate; Lanthanide beta-diketonates; Single-molecule magnet materials

Authors

Bagryanskaya Irina Yu. ^1,2 , Politanskaya Larisa V. ¹ , Tretyakov Evgeny V. ^1,2

Affiliations

1	(Данные Web of science) Vorozhtsov Inst Organ Chem, Ak Lavrentiev Ave 9, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Pirogova St 2, Novosibirsk 630090, Russia

This work provides direct access to the complex [Tb(hfa)(3)(H2O)(2)] with elucidation of the molecular and crystal structure. It has been shown that the interaction of Tb(OAc)(3)center dot 4H(2)O with H-hfa center dot 2H(2)O in water gives {[Tb-2(hfa)(4)(F3CCO2)(2)(H2O)(4)][Tb(hfa)(3)(H2O)(2)](2)center dot H2O), which can be used as a source of pure [Tb(hfa)(3)(H2O)(2)]. This compound is a good quantitative precursor for the synthesis of various Tb(hfa)(3) complexes due to its good solubility in common organic solvents such as hexane, benzene, ether and acetone. Hence, it opens new possibilities in the field of molecular magnetism and design for photonic and optoelectronic applications. (C) 2016 Elsevier B.V. All rights reserved.

Bagryanskaya I.Y. , Politanskaya L.V. , Tretyakov E.V.
Frequently used, but still unknown: Terbium(III) tris-hexafluoroacetylacetonate dihydrate
Inorganic Chemistry Communications. 2016. V.66. P.47-50. DOI: 10.1016/j.inoche.2016.02.009 WOS Scopus РИНЦ

Published print:

Apr 1, 2016

Web of science	WOS:000373415300011
Scopus	2-s2.0-84957941861
Elibrary	27042050
OpenAlex	W2254720151