Synthesis of chloropolyfluoroarenes from polyfluoroarenethiols and PCl5

Synthesis of chloropolyfluoroarenes from polyfluoroarenethiols and PCl5 Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2016, Volume: 52, Number: 2, Pages: 200-205 Pages count : 6 DOI: 10.1134/S1070428016020068

Authors

Nikul'shin P.V. ¹ , Maksimov A.M. ¹ , Platonov V.E. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Pr Acad Lavrenteva 9, Novosibirsk 630090, Russia

Replacement of the thiol group in polyfluoroarenethiols with chlorine was performed by treating with PCl5 as chlorinating agent. By heating in ampules at 200-220A degrees C polyfluoro- and polyfluorochloroarenethiols with PCl5 mono- and dichloropolyfluoroarenes and also 1,2,4-trifluorotrichlorobenzene were synthesized. Dichloropolyfluoroarenes contain chlorine atoms in ortho- and para-positions.

Nikul'shin P.V. , Maksimov A.M. , Platonov V.E.
Synthesis of chloropolyfluoroarenes from polyfluoroarenethiols and PCl5
Russian Journal of Organic Chemistry. 2016. V.52. N2. P.200-205. DOI: 10.1134/S1070428016020068 WOS Scopus РИНЦ

Никульшин П.В. , Максимов А.М. , Платонов В.Е.
Получение хлорполифтораренов из полифторарентиолов и pcl5
Журнал органической химии (RUSS J ORG CHEM+). 2016. Т.52. №2. С.217-221. РИНЦ

Published print:	Feb 1, 2016
Published online:	Apr 5, 2016

Web of science	WOS:000373629400006
Scopus	2-s2.0-84962429972
Elibrary	27150793
OpenAlex	W2397096102