Generation of Perfluoro- and 1-Chloroperfluoro-Indanyl and -Benzocyclobutenyl Cations with Perfluoroalkyl Groups in the Aliphatic Ring

Generation of Perfluoro- and 1-Chloroperfluoro-Indanyl and -Benzocyclobutenyl Cations with Perfluoroalkyl Groups in the Aliphatic Ring Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2019, Volume: 55, Number: 2, Pages: 193-201 Pages count : 9 DOI: 10.1134/S1070428019020118

Tags

fluorinated; chlorine; benzocyclobutene; indane; perfluoroalkyl group; cation

Authors

Mezhenkova T.V. ¹ , Karpov V.M. ¹ , Zonov Ya.V. ^1,2 , Chuikov I.P. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Ul Pirogova 1, Novosibirsk 630090, Russia

Perfluoro(alkylbenzocycloalken-1-yl) cations were generated in a SbF5-SO2ClF medium from perfluorinated indane and benzocyclobutene derivatives containing perfluoroalkyl groups in the alicyclic fragment. The cations exist in equilibrium with their precursors. Adding SO2Cl2 to the system led to the formation of polyfluoroalkylbenzocycloalken-1-yl cations with a chlorine substituent at the cationic center. The structures of the cations were determined by F-19 and C-13 NMR spectroscopy and confirmed by the structures of perfluoroketones formed on their hydrolysis.

Mezhenkova T.V. , Karpov V.M. , Zonov Y.V. , Chuikov I.P.
Generation of Perfluoro- and 1-Chloroperfluoro-Indanyl and -Benzocyclobutenyl Cations with Perfluoroalkyl Groups in the Aliphatic Ring
Russian Journal of Organic Chemistry. 2019. V.55. N2. P.193-201. DOI: 10.1134/S1070428019020118 WOS Scopus РИНЦ

Меженкова Т.В. , Карпов В.М. , Зонов Я.В. , Чуйков И.П.
Генерирование перфтор- и 1-хлорперфторинданильных и -бензоциклобутенильных катионов с перфторалкильными группами в алифатическом кольце
Журнал органической химии (RUSS J ORG CHEM+). 2019. Т.5. №2. С.242-251. DOI: 10.1134/S0514749219020113 РИНЦ

Published print:	Feb 1, 2019
Published online:	Apr 23, 2019

Web of science	WOS:000465521400011
Scopus	2-s2.0-85064818900
Elibrary	38677021
OpenAlex	W2941494230