Synthesis, X-Ray Structure and (Spectro)electrochemical Study of an Electrochromic Iron(II) Chlathrochelate with Tuned Redox Properties

Synthesis, X-Ray Structure and (Spectro)electrochemical Study of an Electrochromic Iron(II) Chlathrochelate with Tuned Redox Properties Full article

Journal

Macroheterocycles
ISSN: 1998-9539

Output data

Year: 2016, Volume: 9, Number: 3, Pages: 257-262 Pages count : 6 DOI: 10.6060/mhc160537b

Tags

Macrocyclic compounds; clathrochelates; iron complexes; ligand reactivity; electrochromism

Authors

Burdukov Aleksey B. ¹ , Sipos Rastislav ² , Pervukhina Natalie V. ¹ , Kuratieva Nataliya V. ¹ , Eltsov Ilia V. ³ , Vershinin Mikhail A. ¹ , Boguslavsky Evgenii G. ¹ , Kal'nyi Danila B. ^1,3 , Selektor Sofia L. ⁴ , Shokurov Alexander V. ⁴ , Voloshin Yan Z. ⁵ , Nefedov Andrei A. ^3,6

Affiliations

1	(Данные Web of science) Nikolaev Inst Inorgan hemistry SB RAS, Novosibirsk 630090, Russia
2	(Данные Web of science) Slovak Univ Technol Bratislava, Bratislava 81237, Slovakia
3	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
4	(Данные Web of science) Frumkin Inst Phys Chem & Electrochem RAS, Moscow 199071, Russia
5	(Данные Web of science) Nesmeyanov Inst Organoelement Cpds RAS, Moscow 119991, Russia
6	(Данные Web of science) Vorozhtsov Novosibirsk Inst Organ Chem SB RAS, Novosibirsk 630090, Russia

A boron-capped tris-dioximate iron(II) bis-macrocyclic clathrochelate with annulated dimethylquinoxaline heterocycle has been synthesized. The compound has been characterized with single-crystal X-ray diffraction, multinuclear NMR, IR, UV-vis spectrometry, CV and spectroelectrochemistry. The clathrochelate is capable of ligand-centered two-electron reversible reduction coupled with electrochromism (in solution and thin film).

Burdukov A.B. , Sipos R. , Pervukhina N.V. , Kuratieva N.V. , Eltsov I.V. , Vershinin M.A. , Boguslavsky E.G. , Kal'nyi D.B. , Selektor S.L. , Shokurov A.V. , Voloshin Y.Z. , Nefedov A.A.
Synthesis, X-Ray Structure and (Spectro)electrochemical Study of an Electrochromic Iron(II) Chlathrochelate with Tuned Redox Properties

Macroheterocycles. 2016. V.9. N3. P.257-262. DOI: 10.6060/mhc160537b WOS Scopus РИНЦ

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