Structure of [Pd-2(H2L1)Cl-4] and [Pd-2(H2L1)Cl-4]aEuro cent 0.5CH(2)Cl(2) compounds with chiral bis-alpha-sulfanyl oxime, a derivative of natural monoterpenoid (+)-3-carene (H(2)l(1))

Structure of [Pd-2(H2L1)Cl-4] and [Pd-2(H2L1)Cl-4]aEuro cent 0.5CH(2)Cl(2) compounds with chiral bis-alpha-sulfanyl oxime, a derivative of natural monoterpenoid (+)-3-carene (H(2)l(1)) Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2015, Volume: 56, Number: 5, Pages: 919-925 Pages count : 7 DOI: 10.1134/S0022476615050145

Tags

complex; bis-alpha-sulfanyl oxime; Pd; crystal and molecular structure

Authors

Kokina T.E. ^1,2 , Glinskaya L.A. ¹ , Gorshkov N.B. ^2,3 , Kuratieva N.V. ^1,2 , Korol'kov I.V. ^1,2 , Tkachev A.V. ^2,3 , Larionov S.V. ^1,2

Affiliations

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk Natl Res State Univ, Novosibirsk, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

The complex of the composition [Pd-2(H2L1)Cl-4] (I) (H2L1 is a chiral bis-alpha-sulfanyl oxime, a derivative of natural monoterpenoid (+)-3-carene) is synthesized. Single crystals of I and solvate [Pd-2(H2L1)Cl-4]aEuro cent 0.5CH(2)Cl(2) (II) are grown. According to the X-ray crystallographic data, the crystal structure of I consists of acentric molecules of the binuclear [Pd-2(H2L1)Cl-4] complex. The structure of solvate II consists of the molecules of binuclear complex I and CH2Cl2 molecules. The PdCl2NS coordination sites are distorted squares (trapezia). In the structures of I and II, the PdCl2 fragments are in the transoid position. In I, the Cl2NS planes of the two coordination sites are nearly parallel (the angle between the planes is 7.7(1)A degrees). The similar angle in solvate II is 22.0(1)A degrees.

Kokina T.E. , Glinskaya L.A. , Gorshkov N.B. , Kuratieva N.V. , Korol'kov I.V. , Tkachev A.V. , Larionov S.V.
Structure of [Pd-2(H2L1)Cl-4] and [Pd-2(H2L1)Cl-4]aEuro cent 0.5CH(2)Cl(2) compounds with chiral bis-alpha-sulfanyl oxime, a derivative of natural monoterpenoid (+)-3-carene (H(2)l(1))
Journal of Structural Chemistry. 2015. V.56. N5. P.919-925. DOI: 10.1134/S0022476615050145 WOS Scopus

Кокина Т.Е. , Глинская Л.А. , Горшков Н.Б. , Куратьева Н.В. , Корольков И.В. , Ткачев А.В. , Ларионов С.В.
Строение соединений [pd 2(h 2l 1)cl 4] и [pd 2(h 2l 1)cl 4]×0,5ch 2cl 2 с хиральным бис-α-сульфанилоксимом - производным природного монотерпеноида (+)-3-карена (h 2l 1)

Журнал структурной химии (J STRUCT CHEM+). 2015. Т.56. №6. С.978-984. DOI: 10.15372/JSC20150514 РИНЦ

Published print:	Sep 1, 2015
Published online:	Dec 16, 2015

Web of science	WOS:000365764600014
Scopus	2-s2.0-84948424763
OpenAlex	W2232880276