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The properties of capillary columns with sorbents based on poly-(1-trimethylsilyl-1-propyne) modified with nitrous oxide Full article

Journal Journal of Chromatography A
ISSN: 0021-9673 , E-ISSN: 1873-3778
Output data Year: 2015, Volume: 1406, Pages: 291-298 Pages count : DOI: 10.1016/j.chroma.2015.06.013
Tags Gas-solid chromatography; Capillary column; Poly-(1-trimethylsilyl-1-propyne) (PTMSP); Modified stationary phase
Authors Patrushev Yuri V. 1,2 , Yakovleva Elena Y. 1,2 , Shundrina Inna K. 3 , Ivanov Dmitry P. 1 , Glazneva Tatyana S. 1,2
Affiliations
1 (Данные Web of science) Boreskov Inst Catalysis, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3 (Данные Web of science) NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

Abstract: In this work, we report the study of properties of capillary columns with a porous layer of the functionalized polymer prepared via oxidation of poly-(1-trimethylsilyl-1-propyne) (PTMSP) by nitrous oxide. It was shown that the double C=C bonds of polymer reacted with nitrous oxide with formation of ketone, carbonyl and hydroxyl groups. The increase in number of those groups in polymer changed a polarity of PTMSP. The change in polarity of polymer led to the selectivity of separations, including oxygen-containing substances. The polarity values were calculated for the prepared columns. It was shown that the total polarity according to McReynolds (AI) was lower than that for known porous polymers. The examples of separations of aliphatic and aromatic hydrocarbons, oxygen- and halogen-containing substances were presented. (C) 2015 Elsevier B.V. All rights reserved.
Cite: Patrushev Y.V. , Yakovleva E.Y. , Shundrina I.K. , Ivanov D.P. , Glazneva T.S.
The properties of capillary columns with sorbents based on poly-(1-trimethylsilyl-1-propyne) modified with nitrous oxide
Journal of Chromatography A. 2015. V.1406. P.291-298. DOI: 10.1016/j.chroma.2015.06.013 WOS Scopus РИНЦ
Dates:
Published print: Aug 1, 2015
Identifiers:
Web of science WOS:000358094200034
Scopus 2-s2.0-84937631559
Elibrary 23991981
OpenAlex W644628921
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