Complexes of Pd(II) and Zn(II) chlorides with anthracene-containing alpha-amino oxime derived from the naturally occurring monoterpenoid (+)-3-carene

Complexes of Pd(II) and Zn(II) chlorides with anthracene-containing alpha-amino oxime derived from the naturally occurring monoterpenoid (+)-3-carene Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2015, Volume: 41, Number: 3, Pages: 162-168 Pages count : 7 DOI: 10.1134/S1070328415030070

Authors

Larionov S.V. ^1,2 , Kokina T.E. ^1,2 , Myachina L.I. ¹ , Glinskaya L.A. ¹ , Rakhmanova M.I. ¹ , Naumov D.Yu. ¹ , Tkachev A.V. ^2,3 , Agafontsev A.M. ^2,3

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

The complex Pd(HL)Cl-2 (I) was obtained (HL is the anthracene-containing chiral alpha-amino oxime derived from the natural monoterpenoid (+)-3-carene). Single crystals of its solvate [Pd(HL)Cl-2] center dot 0.33EtOH (II) were grown. According to X-ray diffraction data (CIF file CCDC no. 1008947), the crystals are built from mononuclear molecules of complex I and uncoordinated EtOH molecules. The coordination environment of the Pd atom in complex I (PdCl2N2) makes up a distorted square (trapezoid). The compound HL acts as a chelating bidentate ligand. The [Pd(HL)Cl-2] and EtOH molecules are united into chains through weak hydrogen bonds. The photoluminescence (PL) of HL and the system ZnCl2-HL in acetonitrile was studied. The emission spectra show three bands at 394, 415, and 440 nm. The photoluminescence of the system ZnCl2-HL in solution is more intense than that of HL. A study of the system ZnCl2-HL by the molar ratio method in conjunction with emission spectroscopy suggests the formation of the complex Zn(HL)Cl-2 in acetonitrile.

Larionov S.V. , Kokina T.E. , Myachina L.I. , Glinskaya L.A. , Rakhmanova M.I. , Naumov D.Y. , Tkachev A.V. , Agafontsev A.M.
Complexes of Pd(II) and Zn(II) chlorides with anthracene-containing alpha-amino oxime derived from the naturally occurring monoterpenoid (+)-3-carene
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2015. V.41. N3. P.162-168. DOI: 10.1134/S1070328415030070 WOS Scopus РИНЦ

Published print:	Mar 1, 2015
Published online:	Mar 5, 2015

Web of science	WOS:000350696500002
Scopus	2-s2.0-84924240013
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