Reduction of nitrotoluenes in supercritical isopropanol over Al2O3 in a flow reactor

Reduction of nitrotoluenes in supercritical isopropanol over Al2O3 in a flow reactor Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2015, Volume: 89, Number: 2, Pages: 202-206 Pages count : DOI: 10.1134/S0036024415020314

Tags

nitrotoluene; toluidine; supercritical isopropanol; aluminum oxide; reduction; hydride transfer; alkoxylation

Authors

Sivcev V. P. ¹ , Korchagina D. V. ² , Volcho K. P. ^2,3 , Salakhutdinov N. F. ^2,3 , Anikeev V. I. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

The reduction of o-, m-, and p-nitrotoluenes in supercritical isopropanol over Al2O3 in a flow reactor is studied. It is shown that corresponding toluidines are major reaction products. Aromatic ring alkoxylation and N-alkylation products make a considerable contribution to the composition of reaction mixtures.

Sivcev V.P. , Korchagina D.V. , Volcho K.P. , Salakhutdinov N.F. , Anikeev V.I.
Reduction of nitrotoluenes in supercritical isopropanol over Al2O3 in a flow reactor
Russian Journal of Physical Chemistry A. 2015. V.89. N2. P.202-206. DOI: 10.1134/S0036024415020314 WOS Scopus РИНЦ

Сивцев В.П. , Корчагина Д.В. , Волчо К.П. , Салахутдинов Н.Ф. , Аникеев В.И.
Восстановление нитротолуолов в сверхкритическом изопропаноле в реакторе проточного типа в присутствии Al2O3
Журнал физической химии (RUSS J PHYS CHEM A+). 2015. Т.89. №2. С.220-224. DOI: 10.7868/S0044453715020314 РИНЦ

Published online:	Dec 30, 2014
Published print:	Feb 1, 2015

Web of science	WOS:000347039900008
Scopus	2-s2.0-84937108839
Elibrary	23990628
OpenAlex	W1978124666