Synthesis of glycidyl ethers derived from terpene alpha-amino oximes and beta-substituted alcohols on their basis

Synthesis of glycidyl ethers derived from terpene alpha-amino oximes and beta-substituted alcohols on their basis Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2015, Volume: 64, Number: 1, Pages: 99-106 Pages count : DOI: 10.1007/s11172-015-0827-4

Tags

glycidyl ethers; beta-amino alcohols; microwave synthesis; nitrosochlorides; mono-terpenes; 3-carene; alpha-pinene; limonene; beta-amino oximes

Authors

Shumilova T. A. ¹ , Agafontsev A. M. ² , Tkachev A. V. ^1,2

Affiliations

1	(Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

3-Carene, alpha-pinene, and limonene alpha-(dimethylamino)oximes were converted to glycidyl ethers at the oxime hydroxyl. The compounds obtained were involved in the reactions with amines, imidazole, as well as with anions of these dimethylamino oximes. The glycidyl ether epoxide ring opening by amines under microwave irradiation conditions proceeds considerably faster than upon convection heating.

Shumilova T.A. , Agafontsev A.M. , Tkachev A.V.
Synthesis of glycidyl ethers derived from terpene alpha-amino oximes and beta-substituted alcohols on their basis
Russian Chemical Bulletin. 2015. V.64. N1. P.99-106. DOI: 10.1007/s11172-015-0827-4 WOS Scopus РИНЦ

Шумилова Т.А. , Агафонцев А.М. , Ткачев А.В.
Синтез глицидиловых эфиров α-аминооксимов терпенового ряда и β-замещенных спиртов на их основе
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2015. №1. С.99. РИНЦ

Published print:	Jan 1, 2015
Published online:	Sep 16, 2015

Web of science	WOS:000361494300016
Scopus	2-s2.0-84942106381
Elibrary	24950392
OpenAlex	W1912619641