Effect of acidity and texture of micro-, mesoporous, and hybrid micromesoporous materials on the synthesis of paramenthanic diol exhibiting anti-Parkinson activity

Effect of acidity and texture of micro-, mesoporous, and hybrid micromesoporous materials on the synthesis of paramenthanic diol exhibiting anti-Parkinson activity Научная публикация

Журнал

Catalysis, Structure and Reactivity
ISSN: 2055-0758 , E-ISSN: 2055-074X

Вых. Данные

Год: 2015, Том: 1, Номер: 3, Страницы: 146-154 Страниц : 9 DOI: 10.1179/2055075815Y.0000000009

Ключевые слова

Zeolites; Hybrid micro-mesoporous materials; MCM-41; MCM-48; Beta zeolites; Verbenol oxide isomerization

Авторы

Torozova A. ^1,2 , Maki-Arvela P. ¹ , Shcherban N.D. ³ , Kumar N. ¹ , Aho A. ¹ , Stekrova M. ¹ , Valkaj K.Maduna ¹ , Sinitsyna P. ^2,3,4 , Filonenko S.M. ³ , Yaremov P.S. ³ , Ilyin V.G. ³ , Volcho K.P. ⁵ , Salakhutdinov N.F. ⁵ , Murzin D.Yu. ¹

Организации

1	(Данные Web of science) Abo Akad Univ, Johan Gadolin Proc Chem Ctr, SF-20500 Turku, Finland
2	(Данные Web of science) Tver State Tech Univ, Tver 170026, Russia
3	(Данные Web of science) Natl Acad Sci, LV Pisarzhevskii Inst Phys Chem, UA-03028 Kiev, Ukraine
4	(Данные Web of science) Tech Univ, St Petersburg State Inst Technol, St Petersburg 190013, Russia
5	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

Microporous, mesoporous, and new hybrid materials were studied in verbenol oxide isomerization for the synthesis of biologically active substance with antiParkinson activity. H-Si-MCM-41, H-Al-MCM-41, H-Al-MCM-48, H-Beta-25, and H-Beta-300 were compared with hybrid materials. The latter with a zeolite-like micromesoporous structure were characterized and evaluated for their catalytic activity for the first time. The approach of dual templating for synthesis of new materials was applied in this work to combine properties of Beta-zeolites and mesoporous cellular foams (MCF). The selectivity to the target product was the highest over microporous mild acidic H-Beta-300 and hybrid ZF-100, with also mild acidity and even absence of strong acid sites. Selectivity at 97 and 99% of conversion was 61 and 59% for H-Beta-300 and hybrid ZF-100, respectively.

Torozova A. , Maki-Arvela P. , Shcherban N.D. , Kumar N. , Aho A. , Stekrova M. , Valkaj K.M. , Sinitsyna P. , Filonenko S.M. , Yaremov P.S. , Ilyin V.G. , Volcho K.P. , Salakhutdinov N.F. , Murzin D.Y.
Effect of acidity and texture of micro-, mesoporous, and hybrid micromesoporous materials on the synthesis of paramenthanic diol exhibiting anti-Parkinson activity
Catalysis, Structure and Reactivity. 2015. V.1. N3. P.146-154. DOI: 10.1179/2055075815Y.0000000009 WOS Scopus OpenAlex

Опубликована в печати:	3 июл. 2015 г.
Опубликована online:	7 янв. 2016 г.

Web of science:	WOS:000433636700006
Scopus:	2-s2.0-84988453685
OpenAlex:	W2263166314

БД	Цитирований
Web of science	9
Scopus	10
OpenAlex	6