Abstract: We present a series of six novel Zn.II) complexes containing anions of perfluorinated biphenyl-4,4'dicarboxylate (oFBPDC2-). Among them are the 0D complex [ Zn.eg) 3].oFBPDC) (eg = ethylene glycol), the 1D [ Zn.H2O).ur).oFBPDC)] (ur = urotropine) and [ Zn.CH3OH) 2.CH3OCH2CH2OH).oFBPDC)] and the 2D layered [ Zn2.CH3CN) 2.oFBPDC) 2] center dot 2C6H6 center dot 2CH3CN, [ Zn2.H2O) 2.oFBPDC) 2] center dot 4.CH3) 2CO, [{Zn4.mu 3-OCH3) 4}.CH3OH) 4.oFBPDC) 2] center dot [{Zn4.mu 3-OCH3) 4}.H2O).CH3OH) 3.oFBPDC) 2] center dot 13CH3OH. The latter coordination polymer is built up by unique Zn4.OCH3) 4 cuboidal units. The complexes are characterized by single-crystal X-ray diffraction, FT-IR, elemental analysis, and TGA. Investigation of the CO2 adsorption at 195 K on [ Zn2.CH3CN) 2.oFBPDC) 2] and [ Zn2.H2O) 2.oFBPDC) 2] of the layered polymeric structure revealed that they have BET surface areas of 334.8 and 150.6 m2 g -1, respectively.

Cite: Cheplakova A.M. , Kovalenko K.A. , Samsonenko D.G. , Vinogradov A.S. , Karpov V.M. , Platonov V.E. , Fedin V.P.
Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4 '-dicarboxylate based on mononuclear, paddle wheel and cuboidal units
CrystEngComm. 2019. V.21. N15. P.2524-2533. DOI: 10.1039/c9ce00073a WOS Scopus РИНЦ OpenAlex

Identifiers:

Web of science:	WOS:000471033200006
Scopus:	2-s2.0-85064081008
Elibrary:	38689084
OpenAlex:	W2916780661

Citing:

DB	Citing
Web of science	15
Scopus	15
Elibrary	19
OpenAlex	16

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