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The influence of the nature of phosphine ligand on palladium catalysts for cross-coupling of weakly nucleophilic potassium pentafluorophenyltrifluoroborate with ArHal and PhCH(2)Hal (Hal=Br, Cl) Full article

Journal Tetrahedron
ISSN: 0040-4020
Output data Year: 2014, Volume: 70, Number: 23, Pages: 3720-3725 Pages count : DOI: 10.1016/j.tet.2014.04.019
Tags Cross-coupling; Palladium catalyst; Bulky phosphine; Polyfluorinated organotrifluoroborates; Aryl halides
Authors Shabalin Anton Yu. 1 , Adonin Nicolay Yu. 1 , Bardin Vadim V. 1,2 , Parmon Valentin N. 1
Affiliations
1 (Данные Web of science) SB RAS, GK Boreskov Inst Catalysis, Novosibirsk 630090, Russia
2 (Данные Web of science) SB RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Abstract: The influence of the ligand nature on catalytic activity of palladium catalysts for cross-coupling of weakly nucleophilic potassium pentafluorophenyltrifluoroborate, which imitates the behavior of electron-deficient organoboron reagents, with aryl halides, ArHal (Hal=Br, Cl) was studied. The activity of the catalysts generated in situ from Pd(OAc)(2) and appropriate phosphorous containing ligands and the reaction selectivity was found to depend on the nature of bulky phosphines used as ligands. As a result, conditions for involving the electron-deficient organoboron reagent-potassium pentafluorophenyltrifluoroborate in the palladium-catalyzed cross-coupling with aryl bromides and aryl chlorides were identified. It was demonstrated that the chosen conditions are appropriate for the reaction of K[C6F5BF3] with benzyl chloride and benzyl bromide deriving pentafluorophenylarylmethanes, C6F5CH2Ar. (C) 2014 Elsevier Ltd. All rights reserved.
Cite: Shabalin A.Y. , Adonin N.Y. , Bardin V.V. , Parmon V.N.
The influence of the nature of phosphine ligand on palladium catalysts for cross-coupling of weakly nucleophilic potassium pentafluorophenyltrifluoroborate with ArHal and PhCH(2)Hal (Hal=Br, Cl)
Tetrahedron. 2014. V.70. N23. P.3720-3725. DOI: 10.1016/j.tet.2014.04.019 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Jun 1, 2014
Identifiers:
Web of science: WOS:000336191600011
Scopus: 2-s2.0-84899965937
Elibrary: 21877201
OpenAlex: W2950267769
Citing:
DB Citing
Web of science 16
Scopus 16
Elibrary 17
OpenAlex 23
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