Silver(I) and gold(I) complexes with tris[2-(2-pyridyeethyl]phosphine

Silver(I) and gold(I) complexes with tris[2-(2-pyridyeethyl]phosphine Full article

Journal

Inorganica Chimica Acta
ISSN: 0020-1693 , E-ISSN: 1873-3255

Output data

Year: 2019, Volume: 494, Pages: 78-83 Pages count : 6 DOI: 10.1016/j.ica.2019.05.015

Tags

Silver(I); Gold(I); Pyridylphosphines; Coordination polymers; Self-assembly; Excitation wavelength dependent photoluminescence

Authors

Baranov Andrey Yu ¹ , Rakhmanova Mariana, I ^1,2 , Samsonenko Denis G. ^1,2 , Malysheva Svetlana F. ³ , Belogorlova Nataliya A. ³ , Bagryanskaya Irina Yu ^2,4 , Fedin Vladimir P. ^1,2 , Artem'ev Alexander, V ^1,2

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, 1 Favorsky Str, Irkutsk 664033, Russia
4	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, 9 Acad Lavrentiev Ave, Novosibirsk 630090, Russia

Coordination abilities of tris[2(2-pyridyeethyl]phosphine (L) toward Ag(I) and Au(I) have been surveyed. Its reaction with AgClO4, AgNO3 and AgOTf results in self-assembly of 1D coordination polymers (CPs) of left perpendicularAg(L)Xright perpendicular(n) type = ClO4, NO3, OTf), built up by conjugated twelve-membered [Ag(((PCCCN) (NCCP))Ag] cycles. The reaction of this phosphine with AgC1 affords CP [Ag4Cl4(L)(2)](n), where in stepped cubane [Ag4Cl4] modules are bridged by "PyCH2CH2P" arms. Interaction of L with Au(tht)Cl produces linear [Au(L)Cl] complex, in which P-coordination is observed. Cps [Ag(L)ClO4] and [Ag4Cl(4)(L)(2)](n) at ambient temperature show pronounced excitation wavelength dependent photoluminescence originated by intraligand transitions.

Baranov A.Y. , Rakhmanova M.I. , Samsonenko D.G. , Malysheva S.F. , Belogorlova N.A. , Bagryanskaya I.Y. , Fedin V.P. , Artem'ev A.V.
Silver(I) and gold(I) complexes with tris[2-(2-pyridyeethyl]phosphine
Inorganica Chimica Acta. 2019. V.494. P.78-83. DOI: 10.1016/j.ica.2019.05.015 WOS Scopus РИНЦ OpenAlex

Published print:

Aug 1, 2019

Web of science:	WOS:000471833200011
Scopus:	2-s2.0-85066092031
Elibrary:	41679382
OpenAlex:	W2944578709

DB	Citing
Web of science	23
Scopus	23
Elibrary	25
OpenAlex	24