Sciact
  • EN
  • RU

Detection of anilines by luminescence spectroscopy using dissolved and adsorbed pyrylocyanine dyes Full article

Journal Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171
Output data Year: 2014, Volume: 63, Number: 3, Pages: 635-641 Pages count : DOI: 10.1007/s11172-014-0485-y
Tags pyrylocyanines; pyridocyanines; aromatic amines; sensors; luminescence
Authors Shelkovnikov V. V. 1 , Kargapolova I. Yu. 1 , Korotaev S. V. 1 , Orlova N. A. 1 , Chuikov I. P. 1 , Nadolinnyi V. A. 2
Affiliations
1 (Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2 (Данные Web of science) Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

Abstract: Reactions of three pyrylocyanine dyes (derived from 2,4,6-trimethylpyrylium perchlorate) with p-toluidine and 2,4-diaminotoluene were studied to develop methods for detection of aromatic amines. The emission spectrum characteristics of the starting dyes and the final products obtained in solution and on silica gel were examined. The presence of open forms of the pyridocyanine dye in acetonitrile was suggested after analyzing the excitation and emission spectra of reaction intermediates. The formation of luminescent pyridocyanine in solution took several days, while its synthesis from the starting dye adsorbed on silica gel was completed within a few seconds.
Cite: Shelkovnikov V.V. , Kargapolova I.Y. , Korotaev S.V. , Orlova N.A. , Chuikov I.P. , Nadolinnyi V.A.
Detection of anilines by luminescence spectroscopy using dissolved and adsorbed pyrylocyanine dyes
Russian Chemical Bulletin. 2014. V.63. N3. P.635-641. DOI: 10.1007/s11172-014-0485-y WOS Scopus РИНЦ OpenAlex
Original: Шелковников В.В. , Каргаполова И.Ю. , Коротаев С.В. , Орлова Н.А. , Чуйков И.П. , Надолинный В.А.
Люминесцентное детектирование анилинов с применением пирилоцианиновых красителей в растворах и адсорбированном состоянии
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2014. №3. С.635. РИНЦ
Dates:
Published print: Mar 1, 2014
Published online: Nov 11, 2014
Identifiers:
Web of science: WOS:000344868100013
Scopus: 2-s2.0-84920928361
Elibrary: 24029839
OpenAlex: W1984829205
Citing:
DB Citing
Web of science 2
Scopus 2
Elibrary 2
OpenAlex 3
Altmetrics: