Synthesis of 4,5-Dialkyl-2-perfluoroaryl-1H-imidazol-1-ols and 4,5-Dimethyl-2-perfluoroaryl-1H-imidazoles Full article
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Output data | Year: 2021, Volume: 57, Number: 12, Pages: 1968-1973 Pages count : 6 DOI: 10.1134/S1070428021120101 | ||
| Tags | 1-hydroxy-1H-imidazoles; 1H-imidazoles; aliphatic α-hydroxyamino oximes; chloroacetone; condensation; perfluoroaromatic aldehydes | ||
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Abstract:
Aliphatic α-hydroxyamino oximes reacted with perfluoroaromatic aldehydes to give α-perfluoroaryl nitrones which underwent cyclization in acetic acid with the formation of 4,5-dialkyl-2-perfluoroaryl-1H-imidazol-1-ols. The latter were also obtained directly from aliphatic α-hydroxyamino oximes and perfluoroaromatic aldehydes in acetic acid without isolation of intermediate nitrones. The reaction of 4,5-dimethyl-2-perfluoroaryl-1H-imidazol-1-ols with chloroacetone afforded 4,5-dimethyl-2-perfluoroaryl-1H-imidazoles.
Cite:
Os’kina I.A.
, Vinogradov A.S.
, Selivanov B.A.
, Savelyev V.A.
, Platonov V.E.
, Tikhonov A.Y.
Synthesis of 4,5-Dialkyl-2-perfluoroaryl-1H-imidazol-1-ols and 4,5-Dimethyl-2-perfluoroaryl-1H-imidazoles
Russian Journal of Organic Chemistry. 2021. V.57. N12. P.1968-1973. DOI: 10.1134/S1070428021120101 WOS Scopus РИНЦ OpenAlex
Synthesis of 4,5-Dialkyl-2-perfluoroaryl-1H-imidazol-1-ols and 4,5-Dimethyl-2-perfluoroaryl-1H-imidazoles
Russian Journal of Organic Chemistry. 2021. V.57. N12. P.1968-1973. DOI: 10.1134/S1070428021120101 WOS Scopus РИНЦ OpenAlex
Original:
Оськина И.А.
, Виноградов А.С.
, Селиванов Б.А.
, Савельев В.А.
, Платонов В.Е.
, Тихонов А.Я.
Синтез 4,5-диалкил-2-перфторарил-1H-имидазол-1-олов и 4,5-диметил-2-перфторарил-1H-имидазолов
Журнал органической химии (RUSS J ORG CHEM+). 2021. Т.57. №12. С.1752-1758. DOI: 10.31857/S0514749221120107 РИНЦ OpenAlex
Синтез 4,5-диалкил-2-перфторарил-1H-имидазол-1-олов и 4,5-диметил-2-перфторарил-1H-имидазолов
Журнал органической химии (RUSS J ORG CHEM+). 2021. Т.57. №12. С.1752-1758. DOI: 10.31857/S0514749221120107 РИНЦ OpenAlex
Dates:
| Submitted: | Jun 30, 2021 |
| Accepted: | Jul 14, 2021 |
| Published print: | Jan 17, 2022 |
Identifiers:
| Web of science: | WOS:000743535900010 |
| Scopus: | 2-s2.0-85123081685 |
| Elibrary: | 48129904 |
| OpenAlex: | W4206245063 |