Reduction of Perfluorinated Benzocycloalkenones and Other Polyfluoroaryl Ketones to Alcohols with LiBH4 Full article
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Output data | Year: 2022, Volume: 58, Number: 6, Pages: 780-790 Pages count : 11 DOI: 10.1134/s1070428022060045 | ||||
| Tags | polyfluorinated alcohol, benzocyclobutenone, indanone, tetralone, reduction, lithium tetrahydroborate | ||||
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Abstract:
The reduction of polyfluorinated benzocycloalken-1-ones, perfluoro-2,3-dihydrobenzofuran-3-one, and perfluorinated diaryl and alkyl aryl ketones with lithium tetrahydridoborate in diethyl ether gave the corresponding alcohols. The reduction of perfluorinated 2-methyl- and 2-hydroxy-2-phenylbenzocyclobutenones was accompanied by opening of the four-membered ring with the formation of (perfluoro-2-vinylphenyl)methanol and [2-(hydroxymethyl)tetrafluorophenyl](pentafluorophenyl)methanol, respectively. Polyfluorinated benzocycloalkenediols were obtained in the reduction of dicarbonyl derivatives of perfluorinated benzocyclobutene, indan, and tetralin.
Cite:
Wang S.
, Golokhvastova D.S.
, Zonov Y.V.
, Karpov V.M.
, Mezhenkova T.V.
, Gatilov Y.V.
Reduction of Perfluorinated Benzocycloalkenones and Other Polyfluoroaryl Ketones to Alcohols with LiBH4
Russian Journal of Organic Chemistry. 2022. V.58. N6. P.780-790. DOI: 10.1134/s1070428022060045 WOS РИНЦ OpenAlex
Reduction of Perfluorinated Benzocycloalkenones and Other Polyfluoroaryl Ketones to Alcohols with LiBH4
Russian Journal of Organic Chemistry. 2022. V.58. N6. P.780-790. DOI: 10.1134/s1070428022060045 WOS РИНЦ OpenAlex
Original:
Ван С.
, Голохвастова Д.С.
, Зонов Я.В.
, Карпов В.М.
, Меженкова Т.В.
, Гатилов Ю.В.
ВОССТАНОВЛЕНИЕ ПЕРФТОРБЕНЗОЦИКЛОАЛКЕНОНОВ И ДРУГИХ ПОЛИФТОРАРИЛКЕТОНОВ В СПИРТЫ ПОД ДЕЙСТВИЕМ LiBH4
Журнал органической химии (RUSS J ORG CHEM+). 2022. Т.58. №6. С.619-631. DOI: 10.31857/S0514749222060040
ВОССТАНОВЛЕНИЕ ПЕРФТОРБЕНЗОЦИКЛОАЛКЕНОНОВ И ДРУГИХ ПОЛИФТОРАРИЛКЕТОНОВ В СПИРТЫ ПОД ДЕЙСТВИЕМ LiBH4
Журнал органической химии (RUSS J ORG CHEM+). 2022. Т.58. №6. С.619-631. DOI: 10.31857/S0514749222060040
Dates:
| Submitted: | Nov 12, 2021 |
| Accepted: | Nov 26, 2021 |
| Published online: | Aug 8, 2022 |
Identifiers:
| Web of science: | WOS:000837686700004 |
| Elibrary: | 53375834 |
| OpenAlex: | W4293150457 |