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Mechanochemical synthesis of organohalogen compounds: a synthetic chemist's view Full article

Journal Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837
Output data Year: 2023, Volume: 92, Number: 9, Article number : 5091, Pages count : DOI: 10.59761/rcr5091
Tags mechanochemistry, halogenation, selectivity, reaction mechanism, green chemistry
Authors Borodkin Gennady Ivanovich 1
Affiliations
1 N.N.Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, prosp. Akademika Lavrentieva 9, 630090 Novosibirsk, Russian Federation

Abstract: Data on the mechanochemical synthesis of halogen-containing organic compounds published mainly over the past 10 years are summarized and critically analyzed. The established views about the methods of activation of mechanochemical halogenation reactions are discussed. The mechanochemical fluorination, chlorination, bromination and iodination reactions of organic compounds are considered. Particular attention is paid to reaction mechanisms, selectivity problem and consideration of the mechanochemical approach as a promising trend of green chemistry. The review is devoted to applications of mechanochemistry in organic synthesis, while the fundamentals of mechanochemistry are beyond the scope of this publication. The bibliography includes 155 references.
Cite: Borodkin G.I.
Mechanochemical synthesis of organohalogen compounds: a synthetic chemist's view
Russian Chemical Reviews. 2023. V.92. N9. 5091 . DOI: 10.59761/rcr5091 WOS Scopus РИНЦ OpenAlex
Original: Бородкин Г.И.
Механохимический синтез галогенорганических соединений: взгляд синтетика
Успехи химии/Uspekhi Khimii. 2023. Т.92. №9. 5091 .
Dates:
Submitted: Jun 9, 2023
Published print: Sep 25, 2023
Published online: Sep 25, 2023
Identifiers:
Web of science: WOS:001078593100002
Scopus: EID:2-s2.0-85173179136
Elibrary: 54519540
OpenAlex: W4385957938
Citing:
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Web of science 2
OpenAlex 2
Elibrary 3
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